This paper analyzes the relationships between the peri-urbanization process in the surroundings of cities and the increase in the synergistic dangers of flooding and water erosion. An analysis and an evaluation of the conditions causing the flooding in peri-urban basins are carried out, comparing the conditions before and after the peri-urbanization process. For this purpose, a diachronic analysis of the morphological and functional conditions of the territory that conditions flooding and associated dangers is provided. The conditions for the generation of runoff, the incorporation of solids into the flood flow, and the characteristics of urban planning are evaluated in 1956 (date before the peri-urbanization process) and 2010 (the peak of the urbanization process in the area) in order to analyze the changes in the land use model and their consequences on the increase in risk. The study is applied to four river basins (44 km2 in total) with varied land use models, in order to collect representative scenarios of the peri-urban coastal basins of the Spanish Mediterranean region. The results show that the risk factors that undergo the most significant changes are the runoff threshold, the vegetation cover, and the soil structure. It is concluded that peri-urbanization constitutes a territorial risk-causing process, and attention is drawn to the convenience of going beyond the sectoral approach in the study of hazards, coming to understand them as a multi-hazard process in which causes have a direct relationship with the underlying territorial model.