Structural properties and supercapacitive performance evaluation of the nickel oxide/graphene/polypyrrole hybrid ternary nanocomposite in aqueous and organic electrolytes

Golkhatmi, Sanaz Zarabi; Sedghi, Arman; Miankushki, Hoda Nourmohammadi; Khalaj, Maryam

doi:10.1016/j.energy.2020.118950

Cited by 37 publications

(14 citation statements)

References 90 publications

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“…A similar observation was made in our previous investigation 64 . Such increase in residual mass might have resulted from structural transition of amorphous (disorder) Ni to crystalline (order) Ni 63,79 . Koltypin et al .…”

Section: Resultssupporting

confidence: 88%

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Layer‐by‐layer preparation of electromagnetic NH₂‐SiO₂/polypyrrole/Ni nanocomposites, characterization and their electrochemical properties

Ali

Rahman

Minami

et al. 2022

Polymer International

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Combinations of organic conducting polymers and inorganic electromagnetic materials have drawn much attention in various fields like energy storage materials, biosensors, biomedical applications, catalysis and removal of heavy metals from water. In this investigation an attempt is made to decorate polypyrrole (PPy), a semiconducting electroactive polymer, with Ni nanoparticles on a functional silica (SiO 2 ) support. First, amine-functionalized mesoporous NH 2 -SiO 2 seed particles are prepared by the sol-gel method using hexamethylenediamine as a surface-functionalizing agent and cetyltrimethylammonium bromide as a template. Second, NH 2 -SiO 2 /PPy composite particles are prepared via in situ seeded chemical oxidative polymerization of pyrrole. The surface of the NH 2 -SiO 2 /PPy composite particles is finally immobilized/doped with Ni nanoparticles via in situ chemical reduction of Ni(II) salt. The surface morphology, structure modification, size distribution and magnetic properties of the prepared NH 2 -SiO 2 /PPy/Ni nanocomposite particles are confirmed using various spectroscopic techniques, electron microscopy, Brunauer-Emmett-Teller measurements, X-ray diffraction and vibrating sample magnetometry. The NH 2 -SiO 2 /PPy/Ni nanocomposite particles possess good paramagnetic properties. A comparative study of electrochemical properties revealed improvement in specific capacitance of NH 2 -SiO 2 /PPy composite compared to PPy but further decoration with Ni nanoparticles under alkaline condition reduces the capacitance value.

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Section: Resultssupporting

confidence: 88%

“…Golkhatmi et al . used graphene to synthesize NiO/graphene/PPy ternary nanocomposites and observed improvement in the electrochemical performance due to the synergic effect and hybrid structure of graphene, NiO and PPy 63 …”

Section: Introductionmentioning

confidence: 99%

Layer‐by‐layer preparation of electromagnetic NH₂‐SiO₂/polypyrrole/Ni nanocomposites, characterization and their electrochemical properties

Ali

Rahman

Minami

et al. 2022

Polymer International

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“…The advantages of GN and UiO-66 were combined in the electrochemical detection of synephrine. This kind of enhancement could be found in reports and previous research ( Golkhatmi et al, 2021 ; Swamy et al, 2021 ). Since nafion was added to the suspension, the formed nafion/UiO-66/GN/SPCE showed a further signal improvement (Green line).…”

Section: Resultssupporting

confidence: 80%

Electrochemical determination of synephrine by using nafion/UiO-66/graphene-modified screen-printed carbon electrode

Zhang

You

Liu

et al. 2022

Current Research in Food Science

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“…This is not only because of the synergistic effects between these electrode materials, but also as a result of the enhanced effective surface area, which in turn reduces the diffusion path length. Many research groups have explored various types of ternary hybrid materials, such as graphene/NiO/PPy [ 43 ], graphene oxide/Fe 2 O 3 /PPy [ 44 ], rGO/MnFe 2 O 4 /PPy [ 45 ], graphene/SnO 2 /PEDOT [ 46 ], graphene/NiO/poly(aniline-co-m-aminophenol) [ 47 ], RGO/ZrO 2 /PPy [ 48 ], and graphene/MoO 3 /PPy [ 49 ], for supercapacitor applications. Most of the conventional synthetic approaches usually produce powdery active materials, and consequently, nonconductive polymeric additives/conductive agents are required to add to the active materials for fabrication of supercapacitor electrodes, which inescapably reduces the content of active materials, as well as affects their electrical conductivity [ 50 , 51 ].…”

Section: Introductionmentioning

confidence: 99%

Fabrication of Flexible Poly(m-aminophenol)/Vanadium Pentoxide/Graphene Ternary Nanocomposite Film as a Positive Electrode for Solid-State Asymmetric Supercapacitors

et al. 2023

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In this study, poly(m-aminophenol) (PmAP) has been investigated as a multi-functional conductive supercapacitor binder to replace the conventional non-conductive binder, namely, poly(vinylene difluoride) (PVDF). The kye benefits of using PmAP are that it is easily soluble in common organic solvent and has good film-forming properties, and also its chemical functionalities can be involved in pseudocapacitive reactions to boost the capacitance performance of the electrode. A new ternary nanocomposite film based on vanadium pentoxide (V2O5), amino-functionalized graphene (amino-FG) and PmAP was fabricated via hydrothermal growth of V2O5 nanoparticles on graphene surfaces and then blending with PmAP/DMSO and solution casting. The electrochemical performances of V2O5/amino-FG/PmAP nanocomposite were evaluated in two different electrolytes, such as KCl and Li2SO4, and compared with those of V2O5/amino-FG nanocomposite with PVDF binder. The cyclic voltametric (CV) results of the V2O5/amino-FG/PmAP nanocomposite exhibited strong pseudocapacitive responses from the V2O5 and PmAP phases, while the faradaic redox reactions on the V2O5/amino-FG/PVDF electrode were suppressed by the inferior conductivity of the PVDF. The V2O5/amino-FG/PmAP electrode delivered a 5-fold greater specific capacitance than the V2O5/amino-FG/PVDF electrode. Solid-state asymmetric supercapacitors (ASCs) were assembled with V2O5/amino-FG/PmAP film as a positive electrode, and their electrochemical properties were examined in both KCl and Li2SO4 electrolytes. Although the KCl electrolyte-based ASC has greater specific capacitance, the Li2SO4 electrolyte-based ASC delivers a higher energy density of 51.6 Wh/kg and superior cycling stability.

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Structural properties and supercapacitive performance evaluation of the nickel oxide/graphene/polypyrrole hybrid ternary nanocomposite in aqueous and organic electrolytes

Cited by 37 publications

References 90 publications

Layer‐by‐layer preparation of electromagnetic NH₂‐SiO₂/polypyrrole/Ni nanocomposites, characterization and their electrochemical properties

Layer‐by‐layer preparation of electromagnetic NH₂‐SiO₂/polypyrrole/Ni nanocomposites, characterization and their electrochemical properties

Electrochemical determination of synephrine by using nafion/UiO-66/graphene-modified screen-printed carbon electrode

Fabrication of Flexible Poly(m-aminophenol)/Vanadium Pentoxide/Graphene Ternary Nanocomposite Film as a Positive Electrode for Solid-State Asymmetric Supercapacitors

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Structural properties and supercapacitive performance evaluation of the nickel oxide/graphene/polypyrrole hybrid ternary nanocomposite in aqueous and organic electrolytes

Cited by 37 publications

References 90 publications

Layer‐by‐layer preparation of electromagnetic NH2‐SiO2/polypyrrole/Ni nanocomposites, characterization and their electrochemical properties

Layer‐by‐layer preparation of electromagnetic NH2‐SiO2/polypyrrole/Ni nanocomposites, characterization and their electrochemical properties

Electrochemical determination of synephrine by using nafion/UiO-66/graphene-modified screen-printed carbon electrode

Fabrication of Flexible Poly(m-aminophenol)/Vanadium Pentoxide/Graphene Ternary Nanocomposite Film as a Positive Electrode for Solid-State Asymmetric Supercapacitors

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Layer‐by‐layer preparation of electromagnetic NH₂‐SiO₂/polypyrrole/Ni nanocomposites, characterization and their electrochemical properties

Layer‐by‐layer preparation of electromagnetic NH₂‐SiO₂/polypyrrole/Ni nanocomposites, characterization and their electrochemical properties