Structural properties of the trimetallic acetylide complex [{Ru(CO)2(η5C5H5)}3(η1:η1:η2:-CC)]+

May, Abdelghani; Ouddaï, Nadia

doi:10.1016/j.crci.2011.11.010

Comptes Rendus. Chimie

2011

DOI: 10.1016/j.crci.2011.11.010

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Structural properties of the trimetallic acetylide complex [{Ru(CO)2(η5C5H5)}3(η1:η1:η2:-CC)]+

Abdelghani May

Nadia Ouddaï

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2012

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The Chemistry of Transition Metal Ethyne-1,2-diyl Complexes

Griffith

Koutsantonis

2012

Aust. J. Chem.

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The chemistry and reactivity of ethyne-1,2-diyl compounds, LnM–CC–MLn, is reviewed. These complexes are simple analogues of organic alkynes, or dimetalloalkynes, and there appears to be no general route to the preparation of these complexes, except perhaps using acid/base methodology. Reactivity patterns, in general, mimic those of simple organic alkynes but have the added dimension of reactive M–C(sp) bonds that sometimes participate in the formation of multimetallic compounds with metal electrophiles.

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The Chemistry of Transition Metal Ethyne-1,2-diyl Complexes

Griffith

Koutsantonis

2012

Aust. J. Chem.

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Structural properties of the trimetallic acetylide complex [{Ru(CO)2(η5C5H5)}3(η1:η1:η2:-CC)]+

Cited by 1 publication

References 16 publications

The Chemistry of Transition Metal Ethyne-1,2-diyl Complexes

The Chemistry of Transition Metal Ethyne-1,2-diyl Complexes

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