The Brookville terrane of southern New Brunswick includes late Precambrian rocks of the Green Head Group, Brookville Gneiss, and Dipper Harbour volcanic unit, and numerous Late Proterozoic to Cambrian granitoid plutons. The Neoproterozoic(?) Green Head Group is a mainly low-grade carbonate-pelite sequence, interpreted to have been deposited on a passive continental margin. It is in faulted contact along a ductile shear zone with the Brookville Gneiss, composed of low-pressure paragneiss, amphibolite, and tonalitic to granodioritic orthogneiss, with minor marble and quartzite. The paragneiss has a maximum depositional age of ca. 640 Ma; the orthogneiss has an igneous crystallization age of ca. 605 Ma, and regional amphibolite facies metamorphism occurred at ca. 564 Ma. The ages indicate that the gneiss is younger than the Green Head Group, but the original relationship between these units is uncertain. The Late Proterozoic Dipper Harbour volcanic unit consists of rhyolitic to andesitic tuffs and rhyolitic flows, with minor interlayered siltstone and marble, preserved in Carboniferous thrust sheets in the southwestern part of the terrane.Plutonic units in the Brookville terrane are dioritic to syenogranitic, I-type, calcalkaline suites with U-Pb zircon and titanite crystallization ages from ca. 555 Ma. to 537 Ma. They are interpreted to have formed in a continental margin subduction zone and appear to represent a more shallow crustal level in the southwest, where they are associated with volcanic rocks of the Dipper Harbour volcanic unit, than in the northeast, where they intrude the Brookville Gneiss and Green Head Group.The Brookville terrane is a late Precambrian to Cambrian tectonostratigraphic terrane, separate from Avalon terrane sensu stricto, and is correlated with the Bras d'Or terrane of Cape Breton Island and areas with rocks of similar age in the Hermitage Flexure of southern Newfoundland.