Structural studies of derivatives of methinyltricobalt enneacarbonyls. V. Crystal structure of bis(methinyltricobalt enneacarbonyl), [CCo3(CO)9]2

Reactions of nickelocene with an Ru5 cluster: crystal structures of two nickel–ruthenium clusters containing C2 ligands

“…6 Two Co 3 clusters linked by a C 2 moiety are found in {Co 3 (CO) 9 } 2 (µ 3 : µ 3 -C 2 ) 11. 7 This paper describes two complexes obtained from the reactions of 1 with nickelocene, having an M 6 C 2 framework related to those found in 2, 8 and 9.…”

Reaction of [PPN][Fe3(CO)CCOC(O)CH3] with the Metal Nucleophile [Re(CO)5]- To Generate a Mixed-Metal Acetylide, [PPN][Fe3(CO)9CCRe(CO)5]

“…Although bimetallic systems are known which are linked by dicarbide units, clusters containing a C 2 fragment are less common . The synthetic pathways to clusters containing a dicarbide unit fall into three categories.…”

The structure of nonacarbonyl-μ3-methylidyne-triangulo-tricobalt. X-ray and neutron diffraction studies

“…Since the X-ray and neutron unit-cell volumes are equal, the temperatures of the two experiments are considered to be about the same. As mentioned (4) Co8(CO)24C 6 2.447 (7) 2.453 (7) 2.462 (7) 2.490 (7) 2.466 (7) 2.468 (7) Dellaca & Penfold (1971) Two sets of equivalent 2.454 (6) Co atoms 2.475 (11) Brice & Penfold (1972) Equivalent Co atoms 2.457 (0.5) Matheson & Penfold (1977) Col-Pax 2.48 (7) (5) 0(13) 0.0333 (2) 0.0362 (6) O. 112 (6) 0(21) 0.0250 (2) 0.0265 (5) 0.088 (5) 0(22) 0.0223 (2) 0.0238 (5) 0.079 (4) 0(23) 0.0220 (2) 0.0238 (5) 0.082 (5) 0(31) 0.0247 (2) 0.0269 (5) 0.098 (5) 0(32) 0.0272 (2) 0.0303 (5) 0.094 (5) 0(33) 0.0257 (2) 0.0282 (7) 0.094 (5) H(1) 0.0325 (3) 0.0267 (6)t -~f Isotropic Ufor H(1) from the X-ray 92 K data.…”