Structural study and physical properties of a new phosphate KCuFe(PO4)2

Badri, Abdessalem; Hidouri, Mourad; López, Marı́a Luisa; Pico, C.; Wattiaux, Alain; Amara, Mongi Ben

doi:10.1016/j.jssc.2011.02.021

Cited by 21 publications

(20 citation statements)

References 22 publications

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“…Completeness of the Fe1 environment is achieved by three orthophosphate tetrahedra connected to the metal atom only by one vertex and one orthophosphate tetrahedron connected via an edge (the Fe1-O distances lie in the range 1.955 (3) to 2.060 (3) Å). In comparison with KCuFe(PO 4 ) 2 (Badri et al, 2011), the bond lengths of Fe2-O are very close in both structures. In KCuFe(PO 4 ) 2 this position is occupied by Fe 3+ , whereas in the structure of KMg 0.09 Fe 1.91 (PO 4 ) 2 it is occupied by both Mg and Fe.…”

Section: Data Collectionmentioning

confidence: 84%

KMg_0.09Fe_1.91(PO₄)₂

et al. 2012

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KMg0.09Fe1.91(PO4)2, potassium [iron(II)/magnesium] iron(III) bis(orthophosphate), is a solid solution derived from compounds with general formula KM IIFe(PO4)2 (M II = Fe, Cu), in which the Mg atoms substitute Fe atoms only in the octahedrally surrounded sites. The framework of the structure is built up from [FeO5] trigonal bipyramids and [MO6] (M = (Fe, Mg) octahedra sharing corners and edges and connected by two types of bridging PO4 tetrahedra. The K+ cations are nine-coordinated and are situated in channels running along [101].

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Section: Data Collectionmentioning

confidence: 84%

KMg_0.09Fe_1.91(PO₄)₂

et al. 2012

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“…It should be emphasized that some members of this family have a number of significant physical properties. Thus, KCuFe[PO 4 ] 2 is an antiferromagnet, also demonstrating the electrochemical properties of conductivity based on the migration of potassium ions through open channels of the crystal structure (Badri et al, 2011).…”

Section: Introductionmentioning

confidence: 87%

Joint crystallization of KCuAl[PO₄]₂ and K(Al,Zn)₂[(P,Si)O₄]₂: crystal chemistry and mechanism of formation of phosphate-silicate epitaxial heterostructure

Yakubovich

Kiriukhina

Shvanskaya

et al. 2020

Acta Crystallogr Sect B

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Two novel phases, potassium copper aluminium bis(phosphate), KCuAl [PO 4 ] 2 (I), and potassium zinc aluminium bis(phosphate-silicate), K(Al,Zn) 2 [(P,Si)O 4 ] 2 (II), were obtained in one hydrothermal synthesis experiment at 553 K. Their crystal structures have been studied using single-crystal X-ray diffraction. (I) is a new member of the A + M 2+ M 3+ [PO 4 ] 2 family. Its open 3D framework built by AlO 5 and PO 4 polyhedra includes small channels populated by columns of CuO 6 octahedra sharing edges, and large channels where K + ions are deposited. It is assumed that the stability of this structure type is due to the pair substitution of Cu/Al with Ni/Fe, Co/Fe or Mg/Fe in different representatives of the series. From the KCuAl[PO 4 ] 2 structural features, one may suppose it is a potentially electrochemically active material and/or possible low-temperature antiferromagnet. In accordance with results obtained from X-ray diffraction data, using scanning electron microscopy, microprobe analysis and detailed crystal chemical observation, (II) is considered as a product of epitaxial intergrowth of phosphate KAlZn[PO 4 ] 2 and silicate KAlSi[SiO 4 ] 2 components having closely similar crystal structures. The assembly of 'coherent intergrowth' is described in the framework of a single diffraction pattern.

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“…The magnetic measurements of the KCuFe-(PO 4 ) 2 representative of the described structure type has revealed the compound to be antiferromagnetic. The investigation of electrical and conductivity properties showed an activation energy of 1.22 eV and the K + ions as the charge carriers (Badri et al, 2011).…”

Section: Tablementioning

confidence: 99%

The rich crystal chemistry of theAMM′(PO₄)₂morphotropic series: NaZnAl(PO₄)₂, the first Na representative with a new structure type

et al. 2019

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A novel phosphate, sodium zinc aluminium bis(phosphate), NaZnAl(PO 4 ) 2 , was obtained under mild-temperature hydrothermal conditions at 553 K. The crystal structure has been studied using single-crystal X-ray experimental data. The pseudo-hexagonal phase NaZnAl(PO 4 ) 2 crystallizes in the monoclinic space group P2 1 /c. Its unique crystal structure is based on a three-dimensional (3D) framework built by Zn-, Al-and P-centred tetrahedra sharing vertices. Channels parallel to the [101] and [101] directions are limited by six-and eight-membered windows, and incorporate Na atoms. The new compound is discussed as a member of the morphotropic series AMM 0 PO 4 , where A = Na, K, Rb or NH 4 , M = Cu, Ni, Co, Fe, Zn or Mg and M 0 = Fe, Al or Ga. The title compound is the first Na representative within the series and is characterized by a 3D architecture of tetrahedra populated in an ordered manner by Zn 2+ , Al 3+ and P 5+ ions. research papers Acta Cryst. (2019). C75, 514-522 Yakubovich et al. First Na representative with a new structure type 515 research papers 522 Yakubovich et al. First Na representative with a new structure type Acta Cryst. (2019). C75, 514-522 supporting information sup-1 Acta Cryst. (2019). C75, 514-522 supporting information Acta Cryst. (2019). C75, 514-522 [https://doi.

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Structural study and physical properties of a new phosphate KCuFe(PO4)2

Cited by 21 publications

References 22 publications

KMg_0.09Fe_1.91(PO₄)₂

KMg_0.09Fe_1.91(PO₄)₂

Joint crystallization of KCuAl[PO₄]₂ and K(Al,Zn)₂[(P,Si)O₄]₂: crystal chemistry and mechanism of formation of phosphate-silicate epitaxial heterostructure

The rich crystal chemistry of theAMM′(PO₄)₂morphotropic series: NaZnAl(PO₄)₂, the first Na representative with a new structure type

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Structural study and physical properties of a new phosphate KCuFe(PO4)2

Cited by 21 publications

References 22 publications

KMg0.09Fe1.91(PO4)2

KMg0.09Fe1.91(PO4)2

Joint crystallization of KCuAl[PO4]2 and K(Al,Zn)2[(P,Si)O4]2: crystal chemistry and mechanism of formation of phosphate-silicate epitaxial heterostructure

The rich crystal chemistry of theAMM′(PO4)2morphotropic series: NaZnAl(PO4)2, the first Na representative with a new structure type

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KMg_0.09Fe_1.91(PO₄)₂

KMg_0.09Fe_1.91(PO₄)₂

Joint crystallization of KCuAl[PO₄]₂ and K(Al,Zn)₂[(P,Si)O₄]₂: crystal chemistry and mechanism of formation of phosphate-silicate epitaxial heterostructure

The rich crystal chemistry of theAMM′(PO₄)₂morphotropic series: NaZnAl(PO₄)₂, the first Na representative with a new structure type