Wettability is an important factor that controls the
position and
transport of fluids in the porous structure of a hydrocarbon reservoir.
Direct quantitative wettability measurement methods include determination
of the contact angle. One of the popular laboratory methods for its
measurement is the sessile drop method, where the droplet of liquid
is set onto the solid sample surface and the angle between liquid
and solid phases in a 2D profile image is measured using a high-resolution
optical subsystem. However, this method has disadvantages connected
with three complex factors: two-dimensionality of data, image resolution,
and the presence of wetting domains on the solid surface. In this
work, we propose a method based on 3D μCT scanning of a sessile
drop on the surface of a material and determination of the value of
the wetting angle using drop height and volume measurements. Since
the contact angle is not measured directly, this makes it possible
to obtain averaged contact angle values for the entire droplet and
leads to more stable values for individual measurements in comparison
with the standard optical method. The results demonstrate that contact
angles obtained using the μCT method differ from the values
obtained by various fitting techniques of the 2D optical method: μCT-values
are higher for hydrophilic interaction by 4–6° and lower
for hydrophobic interaction by 12–17°. Such differences
are associated with the lower susceptibility of the proposed method
to the influence of the gravitational effect, which leads to a flattening
of the droplet shape and distortion of angle measurements on the 2D
projections. However, the described method showed close contact angles
for water drops on a polytetrafluoroethylene surface with values obtained
in microgravity and can be helpful for its prediction. It also has
relatively low sensitivity to the absolute values of the drop volume
and drop segmentation errors.