Structurally diverse manganese(III) complexes of tetradentate N2O2 Schiff-base ligands with ancillary carboxylate donors

Tripodal Trimanganese(III) Complexes of New Unsymmetrical Pentadentate Ligands Derived from 2‐(Salicylideneamino)phenol: Syntheses, Crystal Structures and Properties

“…ORTEP view of 1 showing 30 % probability. [16,[27][28][29][30][31] In addition, coordination environments are very similar to that of [Mn(sap)L] [HL: 2-(2-hydroxyphenyl)benzoxazole], with a five-coordinate square-pyramidal structure, except for a coordinating methanol molecule. [17] It is well known that tridentate H 2 sap derivatives usually form phenoxobridged dinuclear metal complexes.…”

Role of Coordinated Water and Hydrogen‐Bonding Interactions in Stabilizing Monophenoxido‐Bridged Triangular CuIIMII­CuII Compounds (M = Cu, Co, Ni, or Fe) Derived from N,N′‐Ethylenebis(3‐meth­oxysalicylaldimine): Syntheses, Structures, and Magnetic Properties

“…[15][16][17][18] In any case, the second metal center is not coordinated to a water molecule. Moreover, the reported 3d-3d compounds derived from H 2 L-OMe are diphenoxido bridged.…”

“…[19] In the dinuclear unit of these cocrystals, the second metal ion is not linked with the ethoxy oxygen atoms but occupies the O 4 cavity and is coordinated to water molecules, which, in turn, interact with the O 4 cavities of the mononuclear units to form the self-assemblies. With regard to the 3d-3d complexes derived from H 2 L-OMe, a number of dinuclear, [15] trinuclear, [16] tetranuclear, [17] and polymeric [12b,18] compounds have been reported. The second metal ion in these complexes resides either in the O 4 cavity or in between the two O 4 cavities.…”

“…[3, [15][16][17][18][19][20][21] The mononuclear complexes derived from 3-ethoxysalicylaldehydediamine ligands (H 2 L-OEt) are inclusion products where one water molecule is encapsulated in the O 4 compartment. [19,20] In contrast, the only structurally characterized mononuclear copper (II) …”

Crystal structure of chlorido-(2-ethoxy-6-(((quinolin-8-yl)methyl)-phenolato-κ3N,N′,O)-copper(II), C18H15ClCuN2O2

“…Due to their interesting structures and wide potential applicat tions, the schi base complexes have all along attracted much attention, making them play an important role in the development of coordination chemistry as well as inorganic biochemistry, catalysis, optical materials and so on [2][3][4][5][6]. Here, we report the structure of a new copper complex based on an asymmetric tridentate schi base ligand 2-ethoxy-6-((quinolin- [7][8].…”