Structure and absolute configuration of (–)-taylorione, a novel carbon skeletal sesquiterpene ketone of ent-1,10-seco-aromadendrane form, from Mylia taylorii(liverwort)

Application of Pauson–Khand reaction in the total synthesis of terpenes

“…The structure of (+)-taylorione 365 was elucidated and its absolute conguration was determined by combination of its spectral data analysis and degradation investigation. 240 The total synthesis (+)-taylorione 365 was accomplished and reported by Kerr et al in 1996 (ref. 241) 245,246 This tricyclic sesquiterpene 375 is involved in the biosynthesis of neopentalenolactone antibiotic.…”

“…The structure of (+)-taylorione 365 was elucidated and its absolute configuration was determined by combination of its spectral data analysis and degradation investigation. 240 …”