An introduction is given to structure factor determination by means of neutron diffraction.
The method of isotopic substitution, which allows us to separate the partial correlation
functions, is also presented. Suitable instruments, the experimental procedures, and
corrections are described. Other less-conventional techniques such as isomorphic
substitution and anomalous dispersion are also discussed. Finally, examples of the structure
factor determination in chalcogenide, molecular, telluride and phosphate glasses are
discussed in order to illustrate the usefulness of the neutron diffraction technique.