Structure and electrical properties of Ba0.67 Sr0.33TiO3 thin film fabricated by sol-gel based composite technique

Sun, Ling Ling; Tan, Lay Im; Tan, Ooi Kiang; Wang, Zhi Hong; Zhu, Wei

doi:10.1007/s10832-006-9902-4

Cited by 2 publications

(3 citation statements)

References 9 publications

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“…In the first part of this study on STFx, conventional sol-gel method based on the hydrolysis of metal alkoxides was used. In the literature, there are many reports of successful preparation of other perovskite materials using this method, such as (Ba,Sr)TiO3 [207][208][209][210][211][212] and SrTiO3 [213,214]. By extending the understanding from these works, iron (III) nitrate was introduced as precursor due to its common availability and good solubility in water.…”

Section: Conventional Sol-gel Methods Based On Hydrolysis Of Metal Alkmentioning

confidence: 99%

Study of nanostructured semiconductor metal oxide as visible-light photocatalyst

Tan¹

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Since the discovery of the "Fujishima-Honda" effect almost five decades ago, research on photocatalyst effect has been extensive and wide applications have been developed. These include water-splitting, removal of volatile-organic-compounds (VOCs), as well as disinfection for improved air and water quality. In recent years, there have been increasing global awareness to adopt more environmental-friendly approaches. Therefore, photocatalytic oxidation (PCO) process provides a clean alternative for disinfection and removal of environment pollutants and industrial wastes. The current market leader, titanium dioxide (TiO2) is limited by its large bandgap of 3.2 eV to be efficient only under UV light. In this research project, a low-cost and simple process which allows large-scale preparation of nitrogen-doped TiO2 was firstly explored and presented. By oxidizing nano-sized titanium nitride (TiN) powder, mixed phase TiO2 with visible-light absorption up to 525 nm was obtained. The powder oxidized at 500 °C demonstrated good Rhodamine B and gaseous toluene removal; in addition to E. Coli killing under the illumination of fluorescent light with λ > 435 nm. High-resolution X-ray photoelectron spectroscopy (XPS) was used to investigate the binding states of the nitrogen dopants and their effects on the overall photocatalytic performance. The charge separation efficiency was also studied through the powders' surface photovoltage spectra and enhanced separation was observed at higher annealing temperature. Next, this project explored a new, potential candidate for visible-light active semiconductor photocatalyst with tailorable bandgap; in the form of strontium titanate Summary ii ferrite (Sr(Ti1-xFex)O3-δ). Based on previous successful work by our research group on high energy ball-milled Sr(Ti1-xFex)O3-δ nanopowder, the project aim was to develop a fabrication process for Sr(Ti1-xFex)O3-δ thin films using sol-gel approach. Using a modified sol-gel based on Pechini's method of polymerizable metal complex, Sr(Ti1-xFex)O3-δ thin films for the whole range of 0 ≤ x ≤ 1 had been successfully fabricated and characterized for its potential as visible-light photocatalyst. The devised fabrication protocol had produced uniformly coated thin films with good adhesion. The thin films had nanoporous surfaces which are beneficial for applications which require large surface-to-volume ratio. Optical study revealed bandgap reduction from 3.46 eV to 1.10 eV with increasing iron content. However, evaluation of their photocatalytic potential using Rhodamine B, bis-phenol A and stearic acid did not show obvious photocatalytic reaction despite their bandgaps which are in the visible-light range. Further investigation using XPS study showed the formation of oxygen vacancies needed to maintain charge balance. These defects can act as electron traps which prevented charge transfer to the film surface. Furthermore, the electronic conductivity of the films also increased with iron content. As a result, the films were unable to retain charge carriers...

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Section: Conventional Sol-gel Methods Based On Hydrolysis Of Metal Alkmentioning

confidence: 99%

Study of nanostructured semiconductor metal oxide as visible-light photocatalyst

Tan¹

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“…BST thin films of different composition have been prepared by using sol-gel method with different precursors and solvents [63][64][65][66][67][68][69][70][71][72]. The most commonly used precursors as Ba and Sr sources are Ba-and Sr-acetates [Ba(CH3COO) 2 and Sr(CH3COO) 2 ] and alkoxides.…”

Section: Sol-gel Derived Bst Filmmentioning

confidence: 99%

“…It is difficult to deposit films with thickness of more than few hundred nanometers because of crack formation. In this study, a modified sol-gel method has been developed to fabricate crack-free Ba Sr TiO films with thickness of up to several microns which is not achievable by using conventional sol-gel technique [71,72]. This method involves dispersing BST nano-size powders in BST sol-gel precursor using ball mill technique to form a uniform slurry.…”

Section: Fabrication Of the Bst Composite Filmmentioning

confidence: 99%

Impedimetric immunosensor based on humidity sensing properties of BST composite film

Rasouli¹

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Structure and electrical properties of Ba0.67 Sr0.33TiO3 thin film fabricated by sol-gel based composite technique

Cited by 2 publications

References 9 publications

Study of nanostructured semiconductor metal oxide as visible-light photocatalyst

Study of nanostructured semiconductor metal oxide as visible-light photocatalyst

Impedimetric immunosensor based on humidity sensing properties of BST composite film

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