Structure and fragmentation of Ag2H+ and Ag2CH3+

Coordination Chemistry of {[Zr]−Cl−[Zr]}+ Complexes

“…Bending also leads to an increase in steric repulsion, which then counteracts the electronic stabilization. [6] In order to explore possible coordination geometries of The predictions arising from the qualitative molecular orbital arguments are met, [7b] the energetic differences between linear and bent coordination, however, are fairly small. Keeping these results in mind, we now proceed with the analysis of complexes involving the [Cp 3 Zr] ϩ cation (1 ؉ ).…”

Gas-Phase Synthesis and Vibronic Action Spectroscopy of Ag2H+

“…Ag 2 H + represents the smallest reactive prototype which still contains the metal−metal bond in the ground electronic state. It has already been the subject of both experimental , and theoretical − investigations. Concerning its structural properties, most theoretical studies predict that the ground state has a C 2 v geometry with a AgAg bond distance between ∼2.8 , and ∼3.0 Å, in contrast to the D ∞ h geometry proposed earlier .…”

“…It has already been the subject of both experimental , and theoretical − investigations. Concerning its structural properties, most theoretical studies predict that the ground state has a C 2 v geometry with a AgAg bond distance between ∼2.8 , and ∼3.0 Å, in contrast to the D ∞ h geometry proposed earlier . The experimental studies have been focused on the unimolecular fragmentation and ion−molecule reactions with organic substrates in a quadrupole ion trap.…”