Structure and luminescent property of a novel one-dimensional organomercury complex

Liu, Ying; Yan, Pengfei; Yu, Ying‐Hui; Hou, Guang-Feng; Gao, Jin‐Sheng

doi:10.1016/j.inoche.2010.03.005

Cited by 15 publications

(3 citation statements)

References 26 publications

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“…The length of Hg-C bond is 2.058(5)Å, and the length of Hg-Cl bond is 2.328(1)Å, both of which are consistent with similar structures reported previously [25][26][27]. The Hg-O bond distance is 2.981(1)Å, which is signi cantly longer than the commonly reported bond distance (average 2.07Å) [28][29], indicating the existence of a weak chemical bond between Hg and O atoms. Considering the long-term force, Hg atoms form chemical bonds with Cl along the b axis, and the length of the Hg-Cl bond is 3.272(3)Å, which can be considered as electrostatic force.…”

Section: Resultssupporting

confidence: 89%

Structure and germicidal property of a novel guanidine organomercury complex

Liu¹,

Jia²,

Wu³

et al. 2021

Preprint

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A novel guanidine organomercury complex 1, [HgCl(DNP)]·CH5N3·CH3CN 1 (DNP = 2,4- dinitrophenol), has been synthesized. Each mercury(II) atom is tricoordinated to one chlorine atom, one carbon atom of the benzene ring, and one oxygen atom from 2, 4-dinitrophenol. The coordination arrangement around the mercury atom is Y-shaped. This is the first structural report on an organomercury derivative of 2, 4-dinitrophenol and guanidine. The distance of Hg-Cl between the two Hg ions groups is 3.272 Å, which indicates the presence of weak Hg···Cl interactions. Secondary bonds make complex 1 form 3D interspersed network structure, which is 2D [HgCl(DNP)CH5N3]n plane and 1D solvent [(CH3CN)2]∞ broadband. The antibacterial activity of 1 were studied. It shows complex 1 has very good bactericidal activity, and is also a potential antimicrobial agents.

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Section: Resultssupporting

confidence: 89%

Structure and germicidal property of a novel guanidine organomercury complex

Liu¹,

Jia²,

Wu³

et al. 2021

Preprint

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“…Coordination complexes of metal cations with d'" configuration have interesting luminescent properties [27][28][29]39]. In this work, the luminescence of 1, 2, and the corresponding free ligands were investigated in the solid state at room temperature.…”

Section: Photoluminescence Propertiesmentioning

confidence: 99%

“…Interesting luminescence properties of d'" metal complexes such as Cd(II), Hg(II), and Zn(II) have been reported [27][28][29].…”

Section: Introductionmentioning

confidence: 99%

Two Cd(II) complexes derived from mercapto-triazole ligands: syntheses, crystal structures, and luminescent properties

Yang

et al. 2013

Journal of Coordination Chemistry

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Two cadmium complexes, {[Cd(a-ptt)(ptt)]-H2O¡,, (1) and [Cd(a-Hmtt)2(SO4)H2O]-CH3OH (2), have been prepared based on 4-amino-3-(4-pyridine)-5-mercapto-1,2,4-triazole (a-Hptt) and 4-amino-3-methyl-5-mercapto-1,2,4-triazole (a-Hmtt), respectively. In 1, amino-triazole ligand aHptt can partly be deaminated and transformed into 3-(4-pyridine)-5-mercapto-triazole (Hptt) under hydrothermal conditions. X-ray diffraction analysis reveals that I exhibits an unusual 2-D lampshade-type layer structure in which the amino ligand a-ptt and the deamination ligand ptt display eATo-tridentate bridging and bidentate bridging, respectively. Complex 2 is mononuelear and further assembled into a 3-D supramolecular architecture via non-covalent interactions. Complexes 1 and 2 were characterized by elemental analyses, IR, and thermogravimetric analyses. Furthermore, solidstate luminescent properties of 1 and 2 have also been investigated.

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A Luminescent Cage‐Like Complex Constructed by Bidentate Pyridine‐Containing Ligand and Silver Nitrate

Liu

et al. 2012

Zeitschrift anorg allge chemie

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The cage-like complex, Ag 4 L 4 (NO 3 ) 4 (1) [L = 1,4-bis(pyridine-2-ylmethoxy)benzene] was synthesized by the reaction of the flexible bidentate ligand and silver nitrate. It was characterized by elemental analysis, IR spectroscopy, TG, and single-crystal X-ray analysis. 193Complex 1 is reported as the first cage-like cluster constructed by four nitrate anions bridging two [2+2] macrocycles. A blue luminescent emission and luminescent enhancement effect are observed in complex 1.

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Structure and luminescent property of a novel one-dimensional organomercury complex

Cited by 15 publications

References 26 publications

Structure and germicidal property of a novel guanidine organomercury complex

Structure and germicidal property of a novel guanidine organomercury complex

Two Cd(II) complexes derived from mercapto-triazole ligands: syntheses, crystal structures, and luminescent properties

A Luminescent Cage‐Like Complex Constructed by Bidentate Pyridine‐Containing Ligand and Silver Nitrate

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