Co-W nanowires were fabricated by pulsed electrodeposition from a citrate-glycine electrolyte onto rotating cylinder electrodes and into nanoporous polycarbonate membranes. The characterization of the electrodeposition conditions and alloy composition of electrodeposited Co-W alloy thin films were determined and used to guide conditions to electrodeposit the nanowires. Gold nanoparticles of 50 nm size were also added to the electrolyte and deposited during electrodeposition of the Co-W alloy nanowires, embedded within, and attached to the nanowire tip, introducing a novel procedure to attached nanoparticles onto nanowires. Nano-electrodes can be used for various sensing applications, and they can be easily integrated in micro-and nano-scale devices.1 The sensitivity of nano-electrodes depends on the diameter of electrode tip, and the highest sensitivity is observed by most electrochemical methods if the diameter of the working electrode tip is on the same order of the molecular species being detected. To this end, nano-gaping technology has been applied for the fabrication of nano-electrodes that are based on FIB and E-beam lithographic approaches, 2,3 including electrodeposition and/or chemical etching techniques. Gold-based 1D nanostructures (e.g., nanowires, gold nanoparticles) have been recognized as unique materials for electrical and optical sensing applications.5 Gold nanowires can provide high current densities, high signal to noise ratio and low double layer capacitance, 6 while surface plasmon resonance, often exploited with nanoparticles, can uniquely probe interactions of molecules at chemical surfaces and provide label-free bio detection.
5-8Gold nanoparticles (AuNPs) are excellent materials for functionalizing electrode surfaces.9,10 Functionalization can be achieved via the use of bi-functional chemical linking agents, mixing with the components of composite electrodes, covalent binding and others. Notably, gold nanoparticles alone have limited applications in sensing unless surface modification is performed. Careful selection and design of ligands strongly influence the sensitivity and selectivity of a sensor. 5,11 Gold nanoparticles can be synthesized by a citrate reduction method pioneered by Turkevich 12 and later advanced by Frens, 13 with a variety of modification's methods. 6,[14][15][16][17][18] The nanoparticle morphology is dependent upon chemical nanoparticle synthesis methods.Linking agents are typically applied in order to bind gold nanoparticles to surfaces of various substrates. 7,14,[19][20][21][22][23] Surface chemical modification and functionalization using linkers both are attractive methodologies because of highly active and selective layer formation, strong electrode intersectional binding, and changeable physical properties. However, there are a few important disadvantages if linkers are applied in order to design nano-electrodes: additional materials affect surface conductivity and can reduce it or lead to poor electrical contact, and they can shorten an electrode's applica...