Structure and photoluminescence property of two-dimensional coordination polymer complexes involving CuI6X6(X = Cl, Br, I) hexagon prism cluster supported by a tripodal tripyridine ligand with 1,3,5-triethylbenzene spacer

Abstract

Treatment of cuprous halide (Cu(I)X, X = Cl, Br, and I) and a tripodal tripyridine ligand (L) consisting of a 1,3,5-triethylbenzene spacer gave a unique two-dimensional (2D) polymer sheet structure involving a rare Cu(I)(6)X(6) hexagon prism cluster unit, which exhibits intense fluorescence around 448-476 nm.

Designs of 3-Dimensional Networks and MOFs Using Mono- and Polymetallic Copper(I) Secondary Building Units and Mono- and Polythioethers: Materials Based on the Cu–S Coordination Bond

“…X-ray crystallography reveals the presence of 3D network (R3: Fig. 8) using for SBU a not so rare hexagonal prism motif, Cu 6 I 6 [41][42][43][44] but is the only one for bearing S-donors, i.e. Cu 6 I 6 S 6 .…”

Luminescent Coordination Polymers Built Upon Cu4X4 (X=Br,I) Clusters and Mono‐ and Dithioethers

“…In contrast to some other thioether ligands possessing an alkyne function, [54] 6 (m 3 -X) 6 py 6 ] n (X ¼ Cl, Br, I), involving this unusual motif have been reported so far. [55,56] In the latter luminescent material, a pyridine-functionalized triethyl-benzene spacer links the cluster nodes. However, there are some striking differences in the dimensionality (3D vs. 2D) and the CuÁÁÁCu separations between [(Cu 6 I 6 ){m-PhSCH 2 C CCH 2 SPh}] n and the latter two compounds.…”

Crystal Structures of Two New One-Dimensional (1-D) Chained Haloplumbates: [H2dabco][Pb2Br6]·H2O and [Hdabco][PbI3]·H2O (dabco = 1,4-diazabicyclo[2,2,2]octane)

“…Much attention has been paid to the study on design and synthesis of novel organically modified metal halides due to the potential applications in optics [1][2][3][4][5] as well as the structural diversity [6][7][8][9][10]. In general, the organic components modify the metal halides in two kinds of manners: the template and the bridge.…”