Structure and properties of Ionic liquids: Green aspects

Singh, Avtar; Kaur, Nirmaljeet; Parmar, Anupama; Chopra, Harish Kumar

doi:10.1016/b978-0-12-823334-4.00004-7

Cited by 2 publications

References 117 publications

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Merrifield Resin Supported Ionic Liquids: Catalytic Applications in Organic Synthesis

Chopra

Aggarwal

Singh

2023

COC

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Ever since their discovery, Ionic Liquids have raised great interest in organic transformations ranging from solvents to catalytic entities. These belong to a class of nonmolecular compounds composed of ions having curiously low melting points. In the last few years, the Supported Ionic Liquids have drawn the attention of researchers and chemists due to their advantages over homogeneous catalysis. The most commonly used support for immobilized ionic liquids is polymeric. Due to its efficient recovery, reusability and chemical inertness, Merrifield resin can be considered an excellent solid support for ionic liquids. The present review summarizes the synthesis and application of Merrifield Resin Supported Ionic Liquids (MRSILs). The MRSILs can be synthesized by the immobilization of amines like ammonium, choline, imidazolium, DABCO, DMAP, pyridine, and many other functionalized precursors. Additionally, these MRSILs play an incredible role in the field of catalysis, where both metal-free and metal-containing MRSILs are embodied as a catalyst.

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Merrifield Resin Supported Ionic Liquids: Catalytic Applications in Organic Synthesis

Chopra

Aggarwal

Singh

2023

COC

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Design, Synthesis, and Organocatalytic Applications of Functionalized Chiral Ionic Liquids

Verma,

Manhas,

Kapoor

2024

Chiral Ionic Liquids: Applications in Chemistry and Technology

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The functionalized chiral ionic liquids (FCILs) can be considered a sub-class of chiral ionic liquids containing special functional groups for their use in fields like organo-catalysis, separation, purification, etc. The use of FCILs in the field of organocatalysis is particularly important because of the recyclability and high efficiency of these systems. In the current chapter, the applications of functionalized chiral ionic liquids in asymmetric organo-catalysis are summarized with a special emphasis on synthetically important organic reactions like asymmetric Michael reaction, aldol reaction, epoxidation, asymmetric transfer hydrogenation, and Diels-Alder reaction.

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Structure and properties of Ionic liquids: Green aspects

Cited by 2 publications

References 117 publications

Merrifield Resin Supported Ionic Liquids: Catalytic Applications in Organic Synthesis

Merrifield Resin Supported Ionic Liquids: Catalytic Applications in Organic Synthesis

Design, Synthesis, and Organocatalytic Applications of Functionalized Chiral Ionic Liquids

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