Dalton Trans.
 2024
DOI: 10.1039/d4dt01134a
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Structure and redox behaviour of a paramagnetic Rh–Pt–Cu–Pt–Rh heterometallic-extended metal-atom chain

Kazuhiro Uemura,
Yuya Ikeda

Abstract: A paramagnetic, pentanuclear, metal–metal bonded complex comprising three metals is isolated. The Cu dx2−y2 orbital of the Rh–Pt–Cu–Pt–Rh chain contains an unpaired electron. The close energetic levels and symmetric overlap...

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