Khon Kaen Geopark, representing an area of dinosaur fossil diversity, was selected for investigations to reveal the origin and tectonic setting of the Khorat Group. The area occupied by Mesozoic sedimentary rocks of four formal formations of the Khorat Group, namely the Phra Wihan Formation (PWF), Sao Khua Formation (SKF), Phu Phan Formation (PPF), and Khok Kruat Formation (KKF). A field investigation and macroscopic observations suggested that the immature sedimentary rocks of the study area are mainly clast-supported, pebbly sandstone and siltstone with few calcretes. The 50 rock samples that were selected for petrographical and geochemical investigations revealed that the sandstones of the PWF and PPF are quartz arenite and sublitharenite, with some subarkose, whereas those of the SKF are mainly subarkose and sublitharenite. In addition, the KKF dominantly presents sublitharenite with pebbles and calcretes. Mesozoic sandstones contain quartz, feldspars, various types of rock fragments, and accessory minerals (biotite, muscovite, zircon, and tourmaline), with siliceous, ferrous, and calcareous cement. Petrographic (Q–F–L) and geochemical (major and trace element) data suggested that the sources of sediments are mostly quartzose sedimentary rocks and some felsic-intermediate igneous rocks. Chondrite-normalized rare earth element patterns indicated that the origins of the studied sandstones are quartzose sedimentary rocks deposited in a passive continental margin or an upper continental crust. Geochemical traits of the sedimentary successions demonstrated that the provenance of the Khorat Basin prior to reworking by fluvial processes was situated in the passive continental margin or recycled orogen of the paleo-volcanic arc during the Mesozoic period.