Structure co-ordination of solitary amino acids as ligands in metal-organic frameworks (MOFs): A comprehensive review

Biological Metal–Organic Framework-Embedded MXene Nanocomposite as a Wearable Transducer Patch for Real-Time Monitoring of the Sleep Hormone

“…30 Amino acidbased MOFs (Bio-MOFs) in which amino acids are used as the linker molecules can serve as framework systems that can soften the reaction conditions, with the coexistence of Lewis acidic metals, base sites, and hydrogen-bonding groups. 31 Bio-MOFs have been explored in various applications including cryopreservation of cells, antibacterial activity, drug delivery, and cancer therapy. 32 It was established that L-glutamate is a three-connected organic linker that can coordinates with three zinc atoms, and each zinc metal center is connected to six other zinc centers via three glutamate moieties, which can form a six-connected uninodal three-dimensional (3D) coordination net.…”

“…MOFs synthesized solely from natural ligands as well as green solvents could be more environmentally friendly to MOF catalysts and can be proposed as an alternative against toxicity-related concerns . Amino acid-based MOFs (Bio-MOFs) in which amino acids are used as the linker molecules can serve as framework systems that can soften the reaction conditions, with the coexistence of Lewis acidic metals, base sites, and hydrogen-bonding groups . Bio-MOFs have been explored in various applications including cryopreservation of cells, antibacterial activity, drug delivery, and cancer therapy …”

Performance of amine‐functionalized MIL‐53 incorporated thin‐film nanocomposite Pebax membranes for CO2/CH4 mixed gas separation

“…Also, it consists of Al 4 (OH) 2 octahedra infinite chains, which are connected through dicarboxylate groups of benzene dicarboxylate. In this case, the special breathing character of this MOF in the presence of CO 2 makes it an ideal adsorbent for CO 2 storage 30–33 . Also, it is useful to separate CO 2 from CH 4 .…”

“…In this case, the special breathing character of this MOF in the presence of CO 2 makes it an ideal adsorbent for CO 2 storage. [30][31][32][33] Also, it is useful to separate CO 2 from CH 4 . In addition, there is a strong interaction between CO 2 and the MIL-53 hydroxyl group due to the CO 2 quadrupole moment.…”

“…Therefore, this MOF has a high affinity toward CO 2 compared to CH 4. [33][34][35][36][37][38] Modification using amine clusters is a method for improving nanoparticle separation and dispersion within polymer matrix architectures. [39][40][41] Recently, thin-film nanocomposite (TFN) membranes containing a selective thin layer (Pebax 2,533) supported by a high permeable polymer-based material and MOFs have been proposed as an appropriate option to reduce the challenges of filler/polymer compatibility, resulting in increased selectivity while maintaining high permeability.…”