2000
DOI: 10.1080/10426500008045232
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Structure Du Dihydrogéno Hydroxy-1 Éthanebis(phosphonate)-1,1′de Cadmium Dihydrate

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Cited by 9 publications
(14 citation statements)
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“…4b). Although the overall structures of the previously reported Cd complexes 24,28,34,35 and the present compound differ, some similarities are apparent. In all cases the bisphosphonate ligands form six-membered chelate rings with Cd 2+ cations, and the coordination spheres of the metal are similar.…”
Section: Crystal Structure Determinationmentioning
confidence: 45%
“…4b). Although the overall structures of the previously reported Cd complexes 24,28,34,35 and the present compound differ, some similarities are apparent. In all cases the bisphosphonate ligands form six-membered chelate rings with Cd 2+ cations, and the coordination spheres of the metal are similar.…”
Section: Crystal Structure Determinationmentioning
confidence: 45%
“…Previously, some Zn and Cd complexes of methylenebis(phosphonate) MBP, [H 2 C(PO 3 H) 2 ] 2-, and its analogues etidronate, [(CH 3 )(HO)C(PO 3 H) 2 ] 2-, and alendronate, [(NH 3 CH 2 CH 2 CH 2 )(HO)C(PO 3 H) 2 ] 2-, have been reported. [14][15][16][17][18][19][20][21] The structures of these metal complexes are either molecular (monomers and dimers) 17,18,21 or polymeric chains, layers, or three-dimensional networks. [14][15][16][19][20][21] The new metal compounds 1-4, and also the Zn and Cd complexes of the (dichloromethylene)bis(phosphonic acid) P,P′-diethyl ester, 27 are different from the Zn and Cd complexes of MBP and its derivatives etidronate and alendronate.…”
Section: Discussionmentioning
confidence: 99%
“…Usually, the structures are polymeric consisting of chains, layers, pillared layers, or three-dimensional networks, but monomeric structures have also been found. [5][6][7][8][9][10][11][12][13][14][15][16][17][18][19][20][21] The structural properties are dependent on the length and rigidity of the organic group connected to the phosphonate groups and on the number of donor atoms and degree of protonation of the phosphonate group. [1][2][3][4] To affect these properties, organic templates are also used in the preparation of complexes.…”
Section: Introductionmentioning
confidence: 99%
See 1 more Smart Citation
“…(Clearfield, 1998;Zhang & Clearfield, 1997;Alberti et al, 1996;Snover et al, 1996). To study the solid materials, several metal complexes of methylenebisphosphonate, [H 2 C(PO 3 H) 2 ] 2À , and its analogues etidronate, [(CH 3 )(HO)C(PO 3 H) 2 ] 2À , and alendronate, [(NH 3 CH 2 -CH 2 CH 2 )(HO)C(PO 3 H) 2 ] 2À , including some Cd complexes, have been prepared and characterized (Serre & Fé rey, 2002;Barthelet et al, 2000;Sergienko et al, 1998;El Messbahi et al, 2000;Dufau et al, 1995).…”
Section: Commentmentioning
confidence: 99%