The Shuiyindong deposit is one of the ultralarge Carlin-type
gold
deposits in Southwest Guizhou Province, China. Gold mineralization
mainly occurs in the Permian Longtan Formation and the early Triassic
Yelang Formation. It is controlled by both strata and faults. Detailed
studies of the mineralogy and geochemistry characteristics of the
Shuiyindong deposit are conducted to investigate the ore-forming process.
Arsenian pyrite and arsenopyrite are the main Au-hosting minerals.
Three types of pyrite can be recognized, including euhedral and subhedral
pyrite, framboidal pyrite, and bioclastic pyrite. The euhedral and
subhedral pyrite is the main Au-hosting type. The Au appears as a
solid solution (Au+) and natural nanoscale gold (Au0) in the sulfide minerals. The Co/Ni ratios of sulfides (0.07–3.13)
reveal that the ore-forming fluids were mainly affected by hydrothermal
activity, but magmatic activity cannot be excluded. Organic matter
in the ores is abundant (0.11–3.04%), which might provide sulfur
for pyrite and favor an increase in the porosity and permeability
of the host rocks by releasing organic acids. The REE and trace element
results suggest that halogens (F and Cl) were contained in the reducing
magmatic hydrothermal fluids. The sulfur isotopic data (from −8.64‰
to 27.17‰) suggest that the source of sulfur is complicated
and is probably a combination of a magmatic source, the reduction
of marine sulfate, and bacterial sulfate reduction. The Pb isotopic
data of the sulfides indicate that Pb is from a mixture of crust and
mantle sources. The obvious enrichment zones exist along the boundary
faults in the geochemical map of As, implying that As may originate
from the deep crust and then move to the strata with basinal fluids.
By combining these results, it can be inferred that the ore-forming
fluids were a mixture of basinal and deep source fluids. A probable
ore-forming model of the Shuiyindong gold deposit is established.