2012
DOI: 10.1002/smll.201101930
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Structure Formation by Dynamic Self‐Assembly

Abstract: This review summarizes the work conducted in the last decade on the fabrication of mesostructured patterns, which have lateral dimensions within the nano-and microscales, over a wafer-scaled size by means of dynamic self-assembly using Langmuir-Blodgett (LB) transfer or dip-coating. First, strategies to form mesostructures from a homogeneous Langmuir monolayer with controlled shape, size, and patterns alignment will be presented, followed by a detailed theoretical explanation of the pattern formation. In addit… Show more

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Cited by 35 publications
(35 citation statements)
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References 79 publications
(119 reference statements)
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“…Previously, we investigated the LB transfer of DPPC ( l ‐α‐dipalmitoyl‐phosphatidylcholine, molecular structure shown in Scheme ) onto flat solid surfaces . DPPC is one of the major lipid components of biological membranes, which shows a typical phase behavior of a Langmuir monolayer at the air–water interface.…”
Section: Methodsmentioning
confidence: 99%
“…Previously, we investigated the LB transfer of DPPC ( l ‐α‐dipalmitoyl‐phosphatidylcholine, molecular structure shown in Scheme ) onto flat solid surfaces . DPPC is one of the major lipid components of biological membranes, which shows a typical phase behavior of a Langmuir monolayer at the air–water interface.…”
Section: Methodsmentioning
confidence: 99%
“…If these are nonlinear and exhibit negative second derivatives, then the system is thermodynamically unstable over the corresponding concentration range. In such a case a phase decomposition in the bulk film [89] or a surfactant phase transition [90,91] may occur.…”
Section: E Surfactant Phase Transitions and Mixture Decomposition -Bmentioning
confidence: 99%
“…The case of concentration dependent rigidities may also be treated and these result in additional contributions to the variations. Finally, note that the effect of substrate-mediated condensation described in [90,91] naturally results in a free energy f (φ, h) that depends on both φ and h, that is also covered in Appendix B.…”
Section: E Surfactant Phase Transitions and Mixture Decomposition -Bmentioning
confidence: 99%
“…This effect is called substrate-mediated condensation (SMC). Detailed experimental studies show that this transition can occur in a spatially inhomogeneous way, leading to various patterns formed by domains of the two different phases [60,28,46,11]. The range of resulting patterns includes stripes of different orientations and lattice-like patterns.…”
Section: Introductionmentioning
confidence: 99%