Electrochemical corrosion behaviours of as-spun, as-cast, and relaxed Ni 55 Nb 20 Ti 10 Zr 8 Co 7 metallic glasses were investigated in 3 mass% NaCl and 1 N H 2 SO 4 solutions in order to study the effect of different amorphous microstructure. Static immersion tests indicate that the as-spun ribbon possesses the most active state in the NaCl solution at its open circuit potential, followed by the as-cast rod, the relaxed ribbon, and the relaxed rod. While in the H 2 SO 4 solution, the rod samples are more stable than the ribbons, and the relaxed samples exhibit higher stability than the as-quenched samples. The polarization tests revealed slightly higher passive current density (i pass ) for the ribbons than those of the rods in both electrolytes, although no significant differences in i pass were found between the relaxed and the as-quenched specimens. It is concluded that electrochemical corrosion behaviours of metallic glasses are related to the amorphous structure, and a decrease in free volume generally favors corrosion resistance.