Structure-modulated CaFe-LDHs with superior simultaneous removal of deleterious anions and corrosion protection of steel rebar

Abstract

The three anionic species; chloride (Cl−), sulfate (SO42−), and carbonate (CO32−), are typical chemical factors that environmentally accelerate failure of concrete structures with steel rebar through long-term exposure.

Regulating Surface‐Interface Structures of Zn‐Incorporated LiAl‐LDH Supported Ru Catalysts for Efficient Benzene Hydrogenation to Produce Cyclohexene

“…By virtue of structural advantages of LDHs, resulting supported metal catalysts were employed in various catalytic reactions. [24][25][26] Among LDHs, LiAl-LDH, as a unique layered compound containing ordered brucite-like [LiAl 2 (OH) 6 ] + structure, [27,28] exhibit highly crystalline structure and good surface basicity. Therefore, we hypothesize that by the insertion of other metal cations into the brucite-like lattice, modified LiAl-LDH supports will be appropriate to construct supported metal catalysts with tunable surface-interface structures applied in the partial benzene hydrogenation.…”

“…Especially, strong metal‐support interactions can form in LDH‐supported metal catalysts, [22,23] owing to the presence of abundant surface hydroxyls on LDH supports, as well as high surface areas of LDHs. By virtue of structural advantages of LDHs, resulting supported metal catalysts were employed in various catalytic reactions [24–26] . Among LDHs, LiAl‐LDH, as a unique layered compound containing ordered brucite‐like [LiAl 2 (OH) 6 ] + structure, [27,28] exhibit highly crystalline structure and good surface basicity.…”