The incubation time t0 of the crystallization of intrinsic and P, B‐doped amorphous silicon‐germanium (a‐Si1–xGex: H) layers deposited on SiO2/Si(100) substrates is studied as a function of temperature and composition using in situ transmission electron microscopy (TEM). The temperature dependence of t0 follows an Arrhenius behavior t0 = t0* exp (W/kT) with activation energy W and prefactor t0* depending on x. The dependences of grain growth, nucleation rate as well as of the morphology of the polycrystalline films on temperature, doping, and composition are estimated. Doping SiGe films with B decreases grain growth rate during crystallization. Independent of the Ge content, such films stay nanocrystalline (grain size ≪10 nm) up to an annealing temperature of 800°C. During crystallization decomposition within SiGe films is observed. Furthermore, metal‐induced crystallization in the Al/a‐Si1–xGex:H structures is demonstrated.