Structure of Bischloro tris (1, 10‐phenanthroline) copper (II) Dichloromethane Solvate Nonahydrate: [Cu(phen)₃]Cl₂CH₂Cl₂·9H₂O

Abstract

Dichloromethane Solvate Nonahydrate : [ Cu( hen)^] C12. CH2C12 9H20 'Lbe crys&l and d [ a ( I Q * C&Q.gi&O @HEN= l,I&phenanthrdlne) have been de-by x-ray CrystsnOgraphY. complex crystallizes intridiniesystem, spacegrouppi, withlatticeparametersa 85.2970(1),p=66.8400(1), 7 = 83.09(1)", and z=2. 'Ibe =l.zaoOo(3), b = 1.37525(4), c = 1.42750(3)nm, a = coordhted catioas contain a six-coordtrated copper atom chplltprlbythreeF"ligands, andtheJahbTellereffectd tbea(II) ionresuitsinadistododahedralarrangement with the six ClrN distancep ranging h 0.2112(6) to 0.2265(7) 1 1 1 1 1 . In addition to the copper coordinsted cation, there are two chloride ioas, one dichloromethane dvate and nine water molecules in its asymmetric unit. In the solid slate, the titlecompouod forms three dimensid network structures through hydrogen bonds. The intermolecular hydrogen buds coaaect the [ C~(phen)~]'*, chloride ion, dichloromethane dvate and &O moieties altogether.

Oxidation of Benzene Catalyzed by 2,2′-Bipyridine and 1,10-Phenantroline Cu(II) Complexes

“…According to literature, complex 3 can be found in two geometries: a distorted square pyramidal geometry, in which one chlorine atom is interacting with the copper center of another complex molecule, forming a supramolecular structure [23], or a distorted octahedral geometry, where the two chlorine atoms are interacting with the neighbor copper center [24]. It is reported, for complex 4, that copper is hexacoordinated and has an octahedral arrangement with six Cu-N bonds and in addition to the copper coordinated cation, there are two chloride ions [25]. For number 5, copper is pentacoordinated and presents trigonal bipyramidal geometry [26], while in complex number 6 copper is probably hexacoordinated with a phen and two chlorines in a plane and with two chlorines perpendicular to this plane and shared by other copper ions [27].…”