Structure of carbonyl(N-hydroxy-N-nitrosobenzenaminato-O,O')(4-methyl-2,6,7-trioxa-1-phosphabicyclo[2.2.2]octane)rhodium(I)

Di-μ-iodido-bis[acetyl(4-methyl-2,6,7-trioxa-1-phosphabicyclo[2.2.2]octane)(N-nitroso-N-oxidoaniline-κ2O,O′)rhodium(III)]

“…The title compound ( Fig. 1) is the product of the oxidative addition of CH 3 I to [Rh(cupf)(CO){P(OCH 2 ) 3 CCH 3 }] (cupf = cupferrate, (C 6 H 5 N 2 O 2 ) (Basson et al, 1992) which forms part of a series of rhodium complexes used in the kinetic studies of these reactions (Basson et al, 1984;1986b;Steyn et al, 1992;Smit et al, 1994;Roodt & Steyn, 2000).…”

Synthesis, characterization, spectroscopic and crystallographic investigation of metal complexes of N-benzyl-N-nitrosohydroxylamine

“…This ligand is known to form complexes with many metals but only few of them have been structurally characterized [4][5][6][7][8][9][10][11][12][13][14][15].…”

Crystal structure of tris(N-nitroso-N-oxyanilino-κ2 O, O′) oxidoniobium(V), C18H15N6O7Nb

“…The chelate-forming derivatives of this ligand is known to form stable complexes with various metals, but only few of them have been structurally characterized [3][4][5][6][7][8][9][10][11][12]. Also some cupferrates were investigated in our group [13][14][15][16][17][18].…”

“…The chelate-forming derivatives of this ligand is known to form stable complexes with various metals, but only few of them have been structurally characterized [3][4][5][6][7][8][9][10][11][12]. Also some cupferrates were investigated in our group [13][14][15][16][17][18]. This study forms part of ongoing research to investigate the mechanism of the reactions of O,O′-and N,O-bidentate ligands with transition metals used in nuclear industry, such as Hf, Zr, Nb, Ta [19][20][21][22][23][24][25][26].…”