New results obtained in this work from measurements of γ radiation following fission of 248 Cm and 252 Cf, performed using Eurogam2 and Gammashpere arrays, respectively, reveal excitations corresponding to γ vibrations and triaxial deformation present in 100 Zr and 102 Zr nuclei. This is the first observation of non-axial bands in Zr isotopes. Such excitations probably occur due to competing prolate and oblate configurations, identified recently in these nuclei. Evolution of γ softness and triaxiality in Zr isotopes is observed in function of the neutron number.