1990
DOI: 10.1107/s0108270189013156
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Structure of penta(dimethylammonium) undecachlorotricadmate(II)

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Cited by 20 publications
(22 citation statements)
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“…A new crystalline compound with composition [(CH 3 ) 2 NH 2 ] 5 Cd 3 Cl 11 (DMACC) has been reported by Czapla et al [1]. X-ray structural investigations have shown that at room temperature the crystal is of orthorhombic symmetry (the space group Cmcm) [2]. There are four formula units in the unit cell.…”
Section: Introductionmentioning
confidence: 91%
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“…A new crystalline compound with composition [(CH 3 ) 2 NH 2 ] 5 Cd 3 Cl 11 (DMACC) has been reported by Czapla et al [1]. X-ray structural investigations have shown that at room temperature the crystal is of orthorhombic symmetry (the space group Cmcm) [2]. There are four formula units in the unit cell.…”
Section: Introductionmentioning
confidence: 91%
“…Their longest axes coincide with the [100] direction (octahedron I) and with [110] or [110] for the two polyhedra of the second type (octahedron II). The structure of the [Cd 3 Cl 11 ] 5-anion is presented in [2]. The anionic layers are interlinked by two types of dimethylammonium (DMA) cations.…”
Section: Introductionmentioning
confidence: 99%
“…The anionic layers are interlinked by two types of DMA cations. Some dimethylammonium cations are disordered and the phase transitions are most probably related to the changes of their reorientational freedom [1]. The Raman scattering spectra of DMACC confirm disordering of the dimethylammonium group [2].…”
Section: Introductionmentioning
confidence: 72%
“…Besides, the latter should be comparatively weak. Unfortunately, there are no structural data concerning DMACCC but corresponding data for the "pure" DMACC crystal [1] testify that the N-H. . .Cl bonds are comparatively long (3.288-3.576Å) and therefore would be considered as weak ones.…”
Section: Resultsmentioning
confidence: 99%
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