Structure of poly (sodium 4-styrenesulfonate) (PSS) in electrolyte solutions: Theoretical modeling and measurements

Adamczyk, Zbǐgniew; Jachimska, Barbara; Jasiński, Tadeusz; Warszyński, Piotr; Wasilewska, Monika

doi:10.1016/j.colsurfa.2009.01.035

Cited by 50 publications

(62 citation statements)

References 28 publications

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“…For increasing ionic strength, decreasing of the contour implies the folding of the molecule, becoming 3.5 nm for I = 0.03 mol/L, 2.9 nm for I = 0.19 mol/L, and 2.5 nm for I = 0.33 mol/L. A similar behavior was predicted in the simulations of Adamczyk [20,21] , who studied conformations of poly(allylamine hydrochloride) in electrolyte solutions. For the lower ionic strength, the polyelectrolyte chain becomes more extended.…”

Section: Size and Shapesupporting

confidence: 61%

“…The R H and [η] for HM-PAM and HM-HPAM molecules can be calculated through the following equations [20,21] . For the bent spheroid,…”

Section: Size and Shapementioning

confidence: 99%

“…That parameter also facilitates the interpretation of dynamic viscosity measurements in terms of the hydrodynamic theory. The L ef was calculated as a value of the distance between the surfaces of two outermost atoms of the molecule averaged at the fluctuating equilibrium state [20,21] . The procedure of the calculations of [η] of HM-PAM and HM-HPAM is explained in the next part of the paper.…”

Section: Size and Shapementioning

confidence: 99%

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Dynamics simulation on the associative properties of amphiphilic functional monomer modified polyacrylamide copolymers

et al. 2015

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A kind of amphiphilic functional monomer was selected to modify polyacrylamide (PAM) or partially hydrolyzed polyacrylamide (HPAM). The relative properties of the modified polyacrylamide (HM-PAM) and modified partially hydrolyzed polyacrylamide (HM-HPAM) such as radius of gyration (R g ), hydrodynamic radius (R H ), and radial distribution functions (RDFs) have been studied to find the intrinsic relation between the microstructure of the polymer chain and the intrinsic viscosities with changing the amount of modified monomers from 1% to 4%. The simulation results show that, compared to HPAM, HM-HPAM has a better performance in increasing viscosity when the percentage of modified monomers is 2% and has a stronger salt tolerance when the modified monomers is 4%. Furthermore, a complex hydrogen bonding network was revealed with the analysis of radial distribution functions (RDFs) and the pair correlation function was used to investigate the diffusivity of Na + and carbon atoms in the COO -group.

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Section: Size and Shapesupporting

confidence: 61%

“…The R H and [η] for HM-PAM and HM-HPAM molecules can be calculated through the following equations [20,21] . For the bent spheroid,…”

Section: Size and Shapementioning

confidence: 99%

Section: Size and Shapementioning

confidence: 99%

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Dynamics simulation on the associative properties of amphiphilic functional monomer modified polyacrylamide copolymers

et al. 2015

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“…As it is well known, poly(sodium 4-styrenesulphonate) is a strongly charged polyelectrolyte and its charge does not significantly depend on the pH of the system. 23 Hence, above pH = 3.2 PSS was adsorbed on silica particles covered with PAH regardless to the pH. Accordingly, the overall charge of the system SiO 2 /PAH/PSS after the adsorption of poly(sodium 4-styrenesulphonate) was negative in the entire examined pH region (Figure 3).…”

Section: Formation Of Pah/pss/pah Multilayer On Silica Particlesmentioning

confidence: 89%

Electrokinetic Study of Bovine Serum Albumin Adsorption on Previously Formed PAH/PSS Multilayer

Đapić¹,

Kovačević²

2011

Croat. Chem. Acta

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Abstract. Layer-by-layer structures (e.g. polyelectrolyte multilayers and protein-polyelectrolyte multilayers) play a very important role in surface modification processes. In the present study, electrokinetic measurements were applied for the investigation of poly(allylamine hydrochloride)/poly(sodium 4-styrenesulphonate) (PAH/PSS) multilayer formation, with PAH being a terminal layer, as a function of pH. Additionally, the effect of supporting electrolyte (KCl) concentration on multilayer formation was tested. Silica particles were used as the solid substrate. Furthermore, the adsorption of bovine serum albumin (BSA) on previously formed multilayer was examined as a function of pH and BSA concentration. It was confirmed that the electrokinetic measurements are suitable for monitoring the formation of various multilayers. In all investigated systems the process of multilayer formation was found to depend on conditions (ionic strength and pH) under which the multilayer was formed. Moreover, in the case of BSA, the adsorption on previously formed multilayer BSA concentration also plays a significant role. (doi: 10.5562/cca1822)

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“…Therefore, in the absence of salt, PSS chains are essentially expanded and swollen. [28,29] With increase of ionic strength, PSS molecules 'shrink' to a more compact configuration due to a shielding effect of salt cations accompanied by decrease [30] of hydrodynamic radius (R H ) of the polyelectrolyte coil, [31,32] 'ejecting' a portion of solvent (water) and probably forming nonpolar regions. In combination with the formation of a supramolecular guest-host complex between Na + and a cavity formed by ethylene units and oxygen atoms of the crown ether in Mgcr 8 Pc, the generation of nonpolar (hydrophobic) regions in PSS provides an increase of the absorbance of the Q-band at l ~ 680 nm (spectral region of Pc monomer) even in the presence of single PSS.…”

Section: Supramolecular Organization Of Mgсr 8 Pc In Aqueous Environmmentioning

confidence: 99%

Supramolecular Organization of Magnesium Octa[(4’-benzo- 15-crown-5)oxy]phthalocyaninate in Aqueous Solutions of Polyelectrolytes and Surfactants: Analysis by Spectral Methods

Gol’dshleger¹,

Gak²,

Lobach³

et al. 2015

MHC

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Structure of poly (sodium 4-styrenesulfonate) (PSS) in electrolyte solutions: Theoretical modeling and measurements

Cited by 50 publications

References 28 publications

Dynamics simulation on the associative properties of amphiphilic functional monomer modified polyacrylamide copolymers

Dynamics simulation on the associative properties of amphiphilic functional monomer modified polyacrylamide copolymers

Electrokinetic Study of Bovine Serum Albumin Adsorption on Previously Formed PAH/PSS Multilayer

Supramolecular Organization of Magnesium Octa[(4’-benzo- 15-crown-5)oxy]phthalocyaninate in Aqueous Solutions of Polyelectrolytes and Surfactants: Analysis by Spectral Methods

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