Structure of polyethylene gel fibres

Krasnov, Ye.P.; Rudneva, L. D.; Mitchenko, Yu.I.; D’yachkov, A. N.; Kuzub, V.I.; Chegolya, A. S.

doi:10.1016/0032-3950(90)90038-8

Cited by 1 publication

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“…It is well known that gel-and melt-crystallised polyethylene samples demonstrate quite different abilities in plastic deformation and therefore possess various mechanical properties. The discrepancy in drawability is believed to be caused by differences in the initial structure of samples obtained from melt and semi-dilute solution (erroneously called 'gel') [4]. Usually it is attributed to a denser entanglement network in a melt as compared to that in solution from which the gel-cast samples are produced [5].…”

Section: Introductionmentioning

confidence: 99%

Comparison of structure formation upon drawing of gel-cast and melt-crystallised UHMWPE films

et al. 2002

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Structure and mechanical properties of ultra-high molecular weight polyethylene (UHMWPE) films of different draw ratios produced from gel-cast and meltcrystallised samples by multi-stage zone drawing have been studied in order to investigate the structural development and to clarify the role of interfaces between morphological units in the mechanical behaviour. The complex hierarchy of fibrillar structures generating upon neck formation is revealed. It is shown that the rearrangement of initial chain-folded crystallites into a microfibrillar structure occurs inside the volumes of supermolecular structures of larger sizes (spherulites in the melt-crystallised films and stacks of lamellae in the gel-crystallised films), the boundaries between the latter not having disappeared. Both the initial spherulites and stacks of lamellae with internally rearranged microfibrillar structure elongate upon drawing and comprise spindle-like units -macrofibrils -which are well resolved in scanning electron microscopy. Moreover, superfibrils have been revealed in the melt-crystallised films for the first time. They are, as suggested, the remnants of deformed and rearranged nascent polymer particles. Thus, the volume of the drawn films is considered to be full of interfaces. It is suggested that the majority of conformational defects, like chain ends, loops, tie molecules, entanglements, etc., are expelled from fibrillar crystallites in both intra-and interfibrillar regions. In addition to that, the interfibrillar spaces are crossed by tie molecules and micro-and macrofibrils. All of them hinder interfibrillar slip. The differences in creep and recovery of the investigated films are discussed in terms of density of packing and degree of connectivity of various scale fibrillar structural units. The lateral boundaries and the tips of fibrils are considered to be the weakest structural sites from which kink band formation and subsequent fracture of the loaded material begin.

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Section: Introductionmentioning

confidence: 99%