Structure of taxusin

Ho, Tse‐Lok; Lee, G. H.; Peng, Shie Ming; Yeh, Ming-Hsi; Chen, F. C.; Yang, Weiwei

doi:10.1107/s0108270187091819

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1992

2015

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Cited by 8 publications

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“…It should be noted that this is a regenerable source and harvest does not threaten the survival of the species (Denis et al, 1988). Ho et al (1987) reported the crystal structures of the baccatin analogues Taxusin and Taxusin derivatives. In 1992, the structure elucidation and a study of the reactivity of 14-hydroxy-10-deacetyl baccatin III were presented (Appendino et al, 1992).…”

Section: Introductionmentioning

confidence: 99%

Towards validating new enzymatic routes for synthetic conversion: 7,10-bis-O-(2,2,2-trichloroethoxycarbonyl)-10-deacetyl baccatin III–ethyl acetate–water (1/1/1)

Wang

2015

Acta Crystallogr C

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The title compound, C(34)H(38)C(l6)O(14)·C(4)H(8)O(2)·H(2)O, prepared by the reaction of 10-deacetyl baccatin III with 2,2,2-trichloroethyl chloroformate in pyridine, crystallizes via strong intermolecular hydrogen bonds and noncovalent interactions between 7,10-bis-O-(2,2,2-trichloroethoxycarbonyl)-10-deacetyl baccatin III (7,10-di-Troc-DAB), water and ethyl acetate. A detailed comparison of the molecular conformation with those of related structures is presented.

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Section: Introductionmentioning

confidence: 99%