There is investigated the wear resistance of mottled irons with stabilized carbide phase, obtained by alloying iron with copper, chromium and sulfur. It is shown that during heat treatment the outer shell of the carbide phase inclusions, destabilized with copper, dissolves, leaving a core stabilized with chromium. Carbon from the carbide phase dissolution coats the surface of manganese sulphide inclusions, forming additional wear-resistant structural component of mottled iron. The resulting structures can be attributed to compositional structures, which morphology and phase composition can be controlled by alloying and heat treatment.