Structure variation and luminescence of 3D, 2D and 1D lanthanide coordination polymers with 1,3-adamantanediacetic acid

Zhao, Zhi-Peng; Zheng, Kai; Li, Haoran; Zeng, Chenghui; Zhong, Shengliang; Ng, Seik Weng; Zheng, Yi; Chen, Yun

doi:10.1016/j.ica.2018.06.027

Cited by 11 publications

(9 citation statements)

References 59 publications

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“…via in situ co-doping of lanthanide ions into [Bi 2 Cl 6 (pz) 4 ] to form [Bi (2– x ) Ln x Cl 6 (pz) 4 ] (Ln = Sm, Eu, Tb, and Dy), which showed lanthanide-based emission at room temperature, but on cooling to 77 K, bismuth–pyrazine MLCT related bluish-white phosphorescence at 495 nm was revealed . Several other examples based on Eu 3+ and Tb 3+ metal centers exhibiting red and green emission, respectively, are also noted. − …”

Section: Properties and Applicationsmentioning

confidence: 99%

Two-Dimensional Metal-Organic Framework Materials: Synthesis, Structures, Properties and Applications

et al. 2021

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Among the recent developments in metal-organic frameworks (MOFs), porous layered coordination polymers (CPs) have garnered attention due to their modular nature and tunable structures. These factors enable a number of properties and applications, including gas and guest sorption, storage and separation of gases and small molecules, catalysis, luminescence, sensing, magnetism, and energy storage and conversion. Among MOFs, two-dimensional (2D) compounds are also known as 2D CPs or 2D MOFs. Since the discovery of graphene in 2004, 2D materials have also been widely studied. Several 2D MOFs are suitable for exfoliation as ultrathin nanosheets similar to graphene and other 2D materials, making these layered structures useful and unique for various technological applications. Furthermore, these layered structures have fascinating topological networks and entanglements. This review provides an overview of different aspects of 2D MOF layered architectures such as topology, interpenetration, structural transformations, properties, and applications.

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Section: Properties and Applicationsmentioning

confidence: 99%

Two-Dimensional Metal-Organic Framework Materials: Synthesis, Structures, Properties and Applications

et al. 2021

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“…Tb(III) complex 2 displays four main sharp emission bands at 490 nm, 546 nm, 586 nm and 623 nm under the excitation of 332 nm (Figure 6b), which can be assigned to the transitions from the first excited 5 D 4 state to the 7 F J (J=6, 5, 4 and 3) ground-state multiplet. [38][39][40] The most intense peak at 546 nm represents the 5 D 4 ! 7 F 5 transition, which shows the green light emission for Tb(III) ions with a CIE chromaticity coordinate of (0.2755, 0.6054) (Figure S9, Supporting Information).…”

Section: Photoluminescence Propertiesmentioning

confidence: 99%

Synthesis, structures, photoluminescence and magnetic properties of three dinuclear lanthanide(III) complexes derived from 4‐fluorophenylselenoacetic acid

Zhang

et al. 2021

Zeitschrift anorg allge chemie

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Three novel dinuclear lanthanide(III) complexes [Ln 2 L 6 (phen) 2 ] (Ln=Eu III (1), Tb III (2), Dy III (3)), derived from 4-fluorophenylselenoacetic acid and 1,10-phenanthroline, have been synthesized and characterized by elemental analysis, IR, TGA, powder X-ray diffraction and single-crystal X-ray diffraction analysis. Single crystal X-ray diffraction reveal they are isostructural and crystallize in the monoclinic crystal system, space group P2(1)/c. The investigations on luminescent properties of Eu(III) complex 1 and Tb(III) complex 2 exhibit the characteristic emissions of Eu III ( 5 D 0 ! 7 F 0-4 ) and Tb III ( 5 D 4 ! 7 F 6-3 ), and the corresponding luminescent lifetimes are 1.52 and 1.10 ms, respectively. Temperature-dependent photoluminescence studies show the emission intensities and lifetimes for both complexes decrease upon increasing temperature, which indicates complexes 1 and 2 have the potential for sensing temperature. The magnetic studies reveal that Dy(III) complex 3 exhibits weak antiferromagnetic interactions and slow magnetic relaxation behavior.

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“…Three series of lanthanide coordination polymers (Ln-CPs) [1] , 3D Ln-CPs [Tb 2 (ADA) 3 ] n ( 1a , H 2 ADA = 1,3-Adamantane-diacetic Acid), 2D Ln-CPs [Ln 2 (ADA) 3 (dmp) 2 ] n ·2EtOH·H 2 O, (Ln 3+ = Eu 3+ , 2a ; Gd 3+ , 2b ; Tb 3+ , 2c ; dmp = 4,7-dimethyl-1,10-phenanthroline), and 1D Ln-CPs [Ln(ADA)(HADA)(H 2 O)] n (Ln 3+ = Eu 3+ , 3a ; Gd 3+ , 3b ; Tb 3+ , 3c ), by using the ligand H 2 ADA ( Fig. 1 ).…”

Section: Datamentioning

confidence: 99%

“… In this data article, we report the structure, Fourier transform infrared spectroscopy(FT-IR), powder X-ray diffraction (PARD), luminescence decay, thermogravimetric analysis (TGA) and UV–vis data of three series Ln-MOFs. Detailed structure and luminescence properties were discussed in our previous study (Zhao et al, 2018) [1] . The data includes the structure patterns of ligand H 2 ADA, FT-IR, PXRD and thermostability of Ln-MOFs in the air, detailed structure information for these structures are listed in Table 1 , Table 2 , Table 3 , Table 4 , Table 5 , Table 6 , Table 7 .…”

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confidence: 99%

Structural data of structure variation and luminescence of 3D, 2D and 1D lanthanide coordination polymers with 1,3-adamantanediacetic acid

Zeng

Zheng

et al. 2018

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In this data article, we report the structure, Fourier transform infrared spectroscopy(FT-IR), powder X-ray diffraction (PARD), luminescence decay, thermogravimetric analysis (TGA) and UV–vis data of three series Ln-MOFs. Detailed structure and luminescence properties were discussed in our previous study (Zhao et al., 2018) [1]. The data includes the structure patterns of ligand H2ADA, FT-IR, PXRD and thermostability of Ln-MOFs in the air, detailed structure information for these structures are listed in Table 1, Table 2, Table 3, Table 4, Table 5, Table 6, Table 7.

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Structure variation and luminescence of 3D, 2D and 1D lanthanide coordination polymers with 1,3-adamantanediacetic acid

Cited by 11 publications

References 59 publications

Two-Dimensional Metal-Organic Framework Materials: Synthesis, Structures, Properties and Applications

Two-Dimensional Metal-Organic Framework Materials: Synthesis, Structures, Properties and Applications

Synthesis, structures, photoluminescence and magnetic properties of three dinuclear lanthanide(III) complexes derived from 4‐fluorophenylselenoacetic acid

Structural data of structure variation and luminescence of 3D, 2D and 1D lanthanide coordination polymers with 1,3-adamantanediacetic acid

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