Structures of Semiconductor Surfaces and Origins of Surface Reactivity with Organic Molecules

Qu, Yongquan; Han, Keli

doi:10.1002/9781118199770.ch3

Functionalization of Semiconductor Surfaces 2012

DOI: 10.1002/9781118199770.ch3

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Structures of Semiconductor Surfaces and Origins of Surface Reactivity with Organic Molecules

Yongquan Qu

Keli Han

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2016

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Addition of Isocyanides to Tetramesityldigermene: A Comparison of the Reactivity between Surface and Molecular Digermenes

Tashkandi

Cook

Bourque

et al. 2016

Chemistry A European J

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The reaction of benzyl isocyanide, tert-butyl isocyanide, and 2,6-dimethylphenyl isocyanide with tetramesityldigermene (Mes Ge=GeMes ) was examined. Whereas the addition of benzyl isocyanide gave the C-NC activation product, Mes Ge(CH Ph)Ge(CN)Mes , tert-butyl isocyanide, and 2,6-dimethylphenyl isocyanide did not give stable adducts, rather the rate of conversion of the digermene to the corresponding cyclotrigermane was accelerated. A comparison between the reactivity of the isocyanides with Mes Ge=GeMes and the Ge(100)-2×1 surface was made and some insights into the surface chemistry are offered.

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Addition of Isocyanides to Tetramesityldigermene: A Comparison of the Reactivity between Surface and Molecular Digermenes

Tashkandi

Cook

Bourque

et al. 2016

Chemistry A European J

View full text Add to dashboard Cite

show abstract

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Structures of Semiconductor Surfaces and Origins of Surface Reactivity with Organic Molecules

Cited by 1 publication

References 118 publications

Addition of Isocyanides to Tetramesityldigermene: A Comparison of the Reactivity between Surface and Molecular Digermenes

Addition of Isocyanides to Tetramesityldigermene: A Comparison of the Reactivity between Surface and Molecular Digermenes

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