The exciton-polariton, a quasi-particle formed by the coupling of excitons and photons, exhibits a semi-light-semi-matter nature, inheriting the advantages of both constituents and capable of achieving Bose-Einstein condensation at room temperature. This paper investigates the evolution of superposition states of semiconductor microcavity exciton-polariton Bose-Einstein condensate (BEC) within a ring-shaped structure. By employing theoretical modeling, the time-dependent dynamics of the superposition states of exciton-polaritons bound within a unique ring-step asymmetric potential well structure are analyzed. The study reveals correlations between the potential well structure of this step-like configuration and the transitions of exciton-polariton BEC superposition states, shedding light on the evolution paths of BEC systems under specific structural influences and the fluctuation patterns of excitonic fields. These findings hold relevance for experimental manipulations of exciton-polariton superposition states within microcavities. The research demonstrates that ring-step potential well structures influence the excitation and evolution of exciton-polariton BEC superposition states, leading to transitions towards higher or lower order states. This transition is reflected macroscopically in alterations in the number and spatial distribution of interference petals in the superposition states. We consider initial states with orbital angular momentum quantum number l = 2, 3, 4, respectively. By exploiting the different structural relationships of ring-step potential wells, we achieve controlled evolutions of macroscopic occupation states, with interference petal numbers ranging from 4 to 6, 4 to 8, 6 to 8, 6 to 10, 8 to 10, 8 to 12, and 6 to 4.