Strukturen von planaren und tetraedrischen TetrafulminatoMetallkomplexen: [N(C3H7)4]2[Ni(CNO)4], [N(C3H7)4]2[Pt(CNO)4] und [N(C3H7)4]2 [Zn(CNO)4]

Ponikwar, Werner; Mayer, Péter; Piotrowski, Holger; Swoboda, P. A. T.; Oetker, Claus-Jürgen; Beck, Wolfgang

doi:10.1002/1521-3749(200201)628:1<15::aid-zaac15>3.0.co;2-8

Cited by 5 publications

References 9 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

In Search of Fulminate Analogues: L_nM≡CP=NR

Frogley

Hill

Shang

et al. 2020

Chemistry A European J

View full text Add to dashboard Cite

The “CPNR” ligand may be viewed as being isolobal with fulminate, CNO; however, attempts to prepare a complex of such a ligand resulted instead in a range of novel imino and aminophosphinocarbyne complexes. Sequential treatment of [Mo(≡CBr)(CO)2(Tp*)] (Tp*=hydrotris(dimethylpyrazolyl)borate) with nBuLi and ClP=NMes* (Mes*=C6H2tBu3‐2,4,6) afforded mixtures of the complexes [Mo(≡CPnBuNHMes*)(CO)2(Tp*)] and traces of the bimetallic products [Mo2{μ2‐C2P2O(NHMes)2}(CO)4(Tp*)2] and [Mo2(μ2‐C2PNHMes)(CO)4(Tp*)2]. The reaction of [W(≡CBr)(CO)2(Tp*)] with nBuLi and ClP=NMes* afforded predominantly the mononuclear carbyne [W{≡CP(=NMes*)nBu2})(CO)2(Tp*)] and traces of the binuclear complex [W2(μ‐C2PNHMes)(CO)4(Tp*)2] which is also obtained when tBuLi is used. Although not isolable, the intended complexes [M(≡CPNMes*)(CO)2(Tp*)] could be generated in situ and spectroscopically characterized via the reactions of the stannyl carbynes [M(≡CSnnBu3)(CO)2(Tp*)] and ClP=NMes*. The preceding observations are mechanistically interpreted with reference to a computational interrogation of the model complex [Mo(≡CP=NCH3)(CO)2(Tp*)], the LUMO of which has considerable phosphorus character.

show abstract

In Search of Fulminate Analogues: L_nM≡CP=NR

Frogley

Hill

Shang

et al. 2020

Chemistry A European J

View full text Add to dashboard Cite

show abstract

The First Chemical Achievements and Publications by Justus von Liebig (1803−1873) on Metal Fulminates and Some Further Developments in Metal Fulminates and Related Areas of Chemistry

Beck

2003

Eur J Inorg Chem

Self Cite

View full text Add to dashboard Cite

[a]Dedicated to Professor Wolfgang Steglich on the occasion of his 70th birthday for his great friendship, collaboration and support [ ‡ ‡] Keywords: Liebig / Fulminates / Silver / Structure elucidation . DFT calculations have given very good agreement between the calculated and experimental structural parameters and CNO stretching frequencies. The (fulminato)metal complexes closely resemble the analogous cyano compounds.

show abstract