Studies of adsorption and total heterogeneity properties of pure and modified carbon nanotube surfaces

Staszczuk, P.; Rycyk, Magdalena

doi:10.1007/s10973-013-3164-6

Cited by 4 publications

(4 citation statements)

References 18 publications

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“…Monomolecular desorption kinetics in the case of unassociated one-component layers is described by the equation [18]:…”

Section: Estimation Of the Energetic Heterogeneity From Q-tg Datamentioning

confidence: 99%

“…Their determination is important for the processes of diffusion and adsorption, as well as for chemical reactions and catalysis [18,23]. They are determined from data of sorptomatic analysis [24].…”

Section: Estimation Of the Energetic Heterogeneity From Q-tg Datamentioning

confidence: 99%

“…They are determined from data of sorptomatic analysis [24]. The volumetric fractal coefficients were calculated with the method of Frenkel, Helsay, Hill, and Kisielev, from the following equations [18,25]:…”

Section: Estimation Of the Energetic Heterogeneity From Q-tg Datamentioning

confidence: 99%

“…The next phase of modification of the nanotubes was the filling of their cores with cations of metals, such as iron, nickel, and cobalt [17]. Using special thermogravimetry (Q-TG), sorptometry, and AFM methods physicochemical properties of pure and modified by nitric acid and/or ferric nitrate nanotube surface were investigated [18].…”

Section: Introductionmentioning

confidence: 99%

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Studies of modified carbon nanotubes by means of thermogravimetry Q-TG and sorptometry techniques

Staszczuk

Zimmerman-Rysz

2014

J Therm Anal Calorim

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The paper presents the physicochemical (adsorption and porosity) properties of closed carbon nanotubes, opened through the action of an oxidizing acid and modified with metal ions of nickel, cobalt, and iron/ cobalt. The carbon nanotubes were prepared via the oxidation process by means of 65 % nitric acid and/or nickel and cobalt nitrates dissolved with 65 % nitric acid. Using special thermogravimetry Q-TG and sorptometry methods physicochemical properties of pure and modified nanotube surfaces were investigated. A numerical and analytical procedure for the evaluation of heterogeneous properties (adsorption capacity, statistical number of adsorbed liquid layers, desorption energy distribution functions) on the basis of liquid thermodesorption Q-TG from the sample surfaces under the quasi-equilibrium conditions are presented. The calculations of the specific surface areas, pore size and volume, and fractal dimensions of carbon nanotubes were made from sorptometry data.

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“…Monomolecular desorption kinetics in the case of unassociated one-component layers is described by the equation [18]:…”

Section: Estimation Of the Energetic Heterogeneity From Q-tg Datamentioning

confidence: 99%

Section: Estimation Of the Energetic Heterogeneity From Q-tg Datamentioning

confidence: 99%

Section: Estimation Of the Energetic Heterogeneity From Q-tg Datamentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

See 2 more Smart Citations