Studies of Densities, Viscosities and Ultrasonic Speeds of Binary Mixtures Containing Isopropyl Alcohol and Ketones at Different Temperatures

Srinivas, S.; Bai, Baosong; Rao, K. Babu; Narendra, K.; Babu, M. Sarath

doi:10.18052/www.scipress.com/ilcpa.15.151

Cited by 10 publications

(8 citation statements)

References 5 publications

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“…The densities of water at these temperatures were obtained from literature. The viscosity of pure liquids and liquid mixtures at 303.15 K were determined using an Ostwald viscometer [30][31][32][33][34][35] .…”

Section: Methodsmentioning

confidence: 99%

Acoustical Studies on Binary Liquid Mixtures of Some 1,3,4-Oxadiazole Derivatives with Acetone at 303.15 K

Alamelumangai¹,

Santhi²

2013

ILCPA

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The wide spread use of 1,3,4-oxadiazoles as a scaffold in medicinal chemistry establishes this moiety as an important bioactive class of heterocycles. In the present study ultrasonic velocity (u), density (ρ) and viscosity (η) have been measured at frequency 2 MHz in the binary mixtures of 1,3,4-oxadiazole derivatives in acetone at 303.15 K using ultrasonic interferometer technique. The measured value of ultrasonic velocity, density and viscosity have been used to estimate the acoustical parameters namely adiabatic compressibility (β ad ), relaxation time (τ), acoustic impedance (Z i ), free length (L f ), free volume (V f ) and internal pressure (π i ), with a view to investigate the nature and strength of molecular interactions. The obtained result support the occurrence of molecular association through hydrogen bonding in the binary liquid mixtures.

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Section: Methodsmentioning

confidence: 99%

Acoustical Studies on Binary Liquid Mixtures of Some 1,3,4-Oxadiazole Derivatives with Acetone at 303.15 K

Alamelumangai¹,

Santhi²

2013

ILCPA

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“…Molecules at higher temperatures have more energy, thus they can vibrate faster and ultrasonic waves can travel more quickly. The decrease in ultrasonic velocity of honey with increase in quantity of the distilled water can be explained due to the presence of strong attraction between water and honey molecules after mixing [17]. In the case of distilled water, the ultrasonic velocity increases with increase in temperature.…”

Section: Effect Of Temperature On Ultrasonic Velocitymentioning

confidence: 99%

Physicochemical Properties of Indian Honey at Different Concentrations and Temperatures

Kaur¹,

Tarsikka²

2016

IJEAB

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“…2-aminothiazole is used as an intermediate for dyestuff, in photographic chemicals, in medicinal chemistry and its derivatives can find application for treatment gastric ulcer and cancer etc 5 . DMF is an aprotic protophilic and polar solvent used widely in industrial processes, including manufacturing of synthetic fibers, leather, films and in surface coating [6][7][8] . DMF is of particular interest solvents because any significant structural affects are absent due to lack of hydrogen bond.…”

Section: Introductionmentioning

confidence: 99%

Acoustical Studies of Ternary Liquid Mixtures of 2-Aminothiazole in DMF-Water at Different Temperatures

Morey¹,

Naik

2015

ILCPA

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ABSTRACT. The nature and the relative strength of the intermolecular interaction between the components of the liquid mixtures have been successfully investigated by ultrasonic method. In present study, the densities (ρ), ultrasonic velocities (u), viscosity(ɳ) and refractive index(n D ) in a ternary liquid mixture of 2-aminothiazole with N,N-dimethylformamide (DMF) in water have been measured at 303.15, 308.15, 313.15,318.15 and 323.15 K respectively, over the entire composition range by using densitometer, ultrasonic interferometer, viscometer and refractmeter respectively. The measured data have been used to compute the various thermo-acoustic parameters using the standard relations namely, adiabatic compressibility (β s ), intermolecular free length (L f ), specific acoustic Impedance (Z),Wada constant (W), molar sound velocity(R), relative association (R A ), apparent molar compressibility(   ),apparent molar volume( V  )viscosity relaxation time(Г), absorption coefficient, internal pressure (ᴨ),free volume (V f ),Gibb ҆ s free energy(∆G) and specific refraction (r), etc. The results have been analyzed on the basis of variation in thermodynamic parameters. These parameters are useful for explaining the molecular association and interaction between the components of ternary liquid mixtures. The variation in densities and ultrasonic velocities with concentrations in the system show similar trends for evaluated parameters of the constituents in ternary mixture at different temperatures. The results have been interpreted in terms of solute-solvent and solvent-solvent interaction.

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Studies of Densities, Viscosities and Ultrasonic Speeds of Binary Mixtures Containing Isopropyl Alcohol and Ketones at Different Temperatures

Cited by 10 publications

References 5 publications

Acoustical Studies on Binary Liquid Mixtures of Some 1,3,4-Oxadiazole Derivatives with Acetone at 303.15 K

Acoustical Studies on Binary Liquid Mixtures of Some 1,3,4-Oxadiazole Derivatives with Acetone at 303.15 K

Physicochemical Properties of Indian Honey at Different Concentrations and Temperatures

Acoustical Studies of Ternary Liquid Mixtures of 2-Aminothiazole in DMF-Water at Different Temperatures

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