The epoxy spacers in SF 6 Gas Insulated Switchgear (GIS) are vulnerable to discharge. Once the surface of the epoxy spacers is deteriorated under discharge, insulation break down may occur subsequently. From a number of experiments carried out on 110 kV GIS, a new gas CS 2 was detected when creeping discharges occur on the epoxy spacer surface. In order to verify the correlation between CS 2 and the degradation of epoxy spacers, the quantum chemistry analysis was used to investigate the mechanism of CS 2 development. Based on the results, the relation between CS 2 and spacer insulation degradation was determined.