1999
DOI: 10.1002/(sici)1097-461x(1999)75:4/5<449::aid-qua11>3.0.co;2-0
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Studies of hyperpolarizabilities forpara-nitroaniline in the charge-transfer state: Application of a reaction-field response method

Abstract: A multiconfigurational self‐consistent reaction‐field linear response method was utilized to investigate the hyperpolarizabilities of a solute in an electronically excited state. The excited state is the charge‐transfer state in para‐nitroaniline and the calculated hyperpolarizabilities are about a factor of 10 larger than the ones for the ground state of para‐nitroaniline. The hypolarizabilities were calculated as a function of the dielectric constant of the outer medium. Significant solvent influence on the … Show more

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Cited by 9 publications
(9 citation statements)
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“…This finding shows that our usual way of thinking about excited states of push-pull molecules can be erroneous, and lead to dubious predictions and intuitions. p-Nitroaniline is a prototypical push-pull molecule exhibiting a large first hyperpolarizability [5][6][7][8][9][10][11] and nonlinear optical properties with possible applications for electrooptic and second-harmonic generation materials. As a model system, PNA has long been studied both experimentally [4,[12][13][14][15][16][17][18][19][20][21][22] and theoretically.…”
Section: Introductionmentioning
confidence: 99%
“…This finding shows that our usual way of thinking about excited states of push-pull molecules can be erroneous, and lead to dubious predictions and intuitions. p-Nitroaniline is a prototypical push-pull molecule exhibiting a large first hyperpolarizability [5][6][7][8][9][10][11] and nonlinear optical properties with possible applications for electrooptic and second-harmonic generation materials. As a model system, PNA has long been studied both experimentally [4,[12][13][14][15][16][17][18][19][20][21][22] and theoretically.…”
Section: Introductionmentioning
confidence: 99%
“…Some of these effects are described by the so-called polarizable continuum model (PCM), originally elaborated to describe solute-solvent interactions, and of which the extensions include the treatment of anisotropic and ionic media as well as of the Pauli repulsion and dispersion terms. [8][9] Several studies have adopted this scheme to determine the NLO properties of molecules in solution [10][11][12][13] but, to our knowledge, it has not yet been used for molecular crystals.…”
Section: Introductionmentioning
confidence: 99%
“…48 Most citations used the simple self-consistent reaction field methods (SCRF). [18][19][20][21][22][23][24][25][26][27][28][29][30][31][32][33]48 The SCRF methods are based on the reaction field theory, developed by Onsager 49 and Kirkwood. 50 These models have been used with reasonable success, although, there are important limitations.…”
Section: Introductionmentioning
confidence: 99%