2005
DOI: 10.1002/cjoc.200591203
|View full text |Cite
|
Sign up to set email alerts
|

Studies of Iron‐Sulfur Covalency in the Model System and Proteins

Abstract: It was found that the highly covalent nature of the metal-ligand interactions in the Fe-S cluster clearly played an important role in determining the reactivity of the sites. A semi-empirical model, based on the Phillips theory of bonding was developed for quantitative explanation of covalency in Fe-S cluster, showing that Mossbauer spectroscopy and electronic absorption spectroscopy provided the direct experimental probe of covalency of Fe-S 4 clusters.

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
1

Citation Types

0
1
0

Year Published

2006
2006
2015
2015

Publication Types

Select...
6

Relationship

0
6

Authors

Journals

citations
Cited by 7 publications
(1 citation statement)
references
References 20 publications
0
1
0
Order By: Relevance
“…In the last decade, LRSM has been widely studied owing to its sub-wavelength blocking behavior. [2][3][4][5][6][7][8][9][10] However, most of these works focused on the behavior of the local resonance [11][12][13][14][15][16][17] and ignored the Bragg scattering effects provided by the periodic structure, as these typically occur at frequencies much higher than those of the resonances. Hence, the periodic arrangement of LRs has not been fully utilized.…”
Section: Introductionmentioning
confidence: 99%
“…In the last decade, LRSM has been widely studied owing to its sub-wavelength blocking behavior. [2][3][4][5][6][7][8][9][10] However, most of these works focused on the behavior of the local resonance [11][12][13][14][15][16][17] and ignored the Bragg scattering effects provided by the periodic structure, as these typically occur at frequencies much higher than those of the resonances. Hence, the periodic arrangement of LRs has not been fully utilized.…”
Section: Introductionmentioning
confidence: 99%