Studies of kinetics of indirect in situ electrocatalytic oxidation of aliphatic alcohols to carboxylic acids by active forms of oxygen

Kosheleva, A. M.; Maksimov, N. G.; Kornienko, G. V.; Kornienko, V. L.

doi:10.1134/s1023193515110075

Cited by 3 publications

(1 citation statement)

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“…Nickel complexes are known to catalyze certain oxidation reactions of hydrocarbons [25,26,27,28,29,30,31,32,33,34,35,36,37] and alcohols [38,39,40,41,42,43,44] by peroxides. We have tested the catalytic effect of compound 1 in oxidations with various oxidants.…”

Section: Resultsmentioning

confidence: 99%

Novel Cage-Like Hexanuclear Nickel(II) Silsesquioxane. Synthesis, Structure, and Catalytic Activity in Oxidations with Peroxides

et al. 2016

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New hexanuclear nickel(II) silsesquioxane [(PhSiO 1.5 ) 12 (NiO) 6 (NaCl)] (1) was synthesized as its dioxane-benzonitrile-water complex (PhSiO 1,5 ) 12 (NiO) 6 (NaCl)(C 4 H 8 O 2 ) 13 (PhCN) 2 (H 2 O) 2 and studied by X-ray and topological analysis. The compound exhibits cylinder-like type of molecular architecture and represents very rare case of polyhedral complexation of metallasilsesquioxane with benzonitrile. Complex 1 exhibited catalytic activity in activation of such small molecules as light alkanes and alcohols. Namely, oxidation of alcohols with tert-butylhydroperoxide and alkanes with meta-chloroperoxybenzoic acid. The oxidation of methylcyclohexane gave rise to the isomeric ketones and unusual distribution of alcohol isomers.

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