“…The k parameter has been related to the strength of the interactions between both components [48,49]; i.e. for systems where the chain mobility is impeded by the interactions values higher than 1 are usually obtained for k: In our case, k parameter takes a value of 1.37, which reflects the strong interactions present in the T/PVPh blend, in good agreement to the values obtained for other mixtures constituted by PVPh [50].…”
Section: Effect Of Additives In the Free Volume Of Trogamidmentioning
“…The k parameter has been related to the strength of the interactions between both components [48,49]; i.e. for systems where the chain mobility is impeded by the interactions values higher than 1 are usually obtained for k: In our case, k parameter takes a value of 1.37, which reflects the strong interactions present in the T/PVPh blend, in good agreement to the values obtained for other mixtures constituted by PVPh [50].…”
Section: Effect Of Additives In the Free Volume Of Trogamidmentioning
“…In fact, it is an adjusting parameter which has been served as a semi-quantitative measurement of the interaction strength between the mixed components [28,29]. Fig.…”
Section: Glass Transition Temperatures ðT G Sþmentioning
“…5, the experimental values of T g can be satisfactorily fitted to a Gordon-Taylor equation [8,9,16]: where T g o and T g r are the glass transition temperatures of the individual components, oil and resin, v o and v r are their respective volume fractions, and k is a non-dimensional semi-empirical parameter, with a value of 1.72 for the blends studied. This last parameter is the ratio between the differences in the thermal expansion coefficients of the rubbery and the glassy states for components 1 and 2.…”
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