2001
DOI: 10.1016/s0378-7753(00)00575-9
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Studies on activated carbon capacitor materials loaded with different amounts of ruthenium oxide

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Cited by 92 publications
(52 citation statements)
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“…have been intensively studied as ES materials. 123,192,193,209,213,221,223,231,233,234,[245][246][247][248][249][250][251][252][253][254][255][256][257][258][259][260][261][262] The quantity of RuO 2 required in the electrode layer has thereby been reduced significantly, and higher specific capacitances have been achieved, such as 256 201 It is necessary to point out that many investigators utilized a very high annealing temperature to obtain RuO 2 /carbon composites. 247 Obviously, as mentioned previously, high temperature will lead to higher crystallinity, compromising the utilization of RuO 2 .…”
Section: Ruomentioning
confidence: 99%
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“…have been intensively studied as ES materials. 123,192,193,209,213,221,223,231,233,234,[245][246][247][248][249][250][251][252][253][254][255][256][257][258][259][260][261][262] The quantity of RuO 2 required in the electrode layer has thereby been reduced significantly, and higher specific capacitances have been achieved, such as 256 201 It is necessary to point out that many investigators utilized a very high annealing temperature to obtain RuO 2 /carbon composites. 247 Obviously, as mentioned previously, high temperature will lead to higher crystallinity, compromising the utilization of RuO 2 .…”
Section: Ruomentioning
confidence: 99%
“…It was also reported that RuO 2 particles prepared via NaHCO 3 titration were smaller than those produced by NaOH titration. 212 According to Ramani et al, 213 varying the deposition temperature and/or pH can control the cluster size in the process of electroless deposition. Using a template method, the particle size of RuO 2 ÁxH 2 O can be controlled by altering the template size.…”
mentioning
confidence: 99%
“…The electrodes have been prepared from: (i) carbons with different porosity and different specific surface areas, e.g. carbon aerogel [1,2], activated carbons [3][4][5][6][7][8], mesopore-templated carbon [9][10][11], carbon black [12][13][14], glassy carbon [15,16], carbon nanotubes [17][18][19][20][21][22][23][24][25][26][27], carbon nanofibres [28,29], and others [30,31], (ii) different precursors for RuO 2 ·xH 2 O, e.g. RuCl 3 ·0.5H 2 O or Ru(acac) 3 , and hence different procedures: a sol-gel followed by neutralization in the case of RuCl 3 ·0.5H 2 O and an electrochemical oxidation in the case of Ru(acac) 3 , and (iii) different contents (or loads) in RuO 2 ·xH 2 O.…”
Section: Introductionmentioning
confidence: 99%
“…The capacitive behaviour of hydrous RuO 2 is attributable to several parameters such as surface area, water content, electronic conductivity and nanocrystalline nature [18,19]. However, hydrous ruthenium oxide is an expensive material and hence much effort has been expended to replace ruthenium oxide by suitable cheaper nanostructured transition metal oxides such as MnO 2 , Fe 3 O 4 and V 2 O 5 for aqueous electrochemical supercapacitors.…”
Section: Introductionmentioning
confidence: 99%