The
effect of biomass (Eucalyptus globulus, pine
cones, and Brassica rapa) composition on the γ-irradiation
behavior of some polypropylene (PP) biocomposites has been studied.
The variations in mechanical properties, contact angles, crystallinity
index, hydroxyl and carbonyl indices, and induction period of the
oxidative process indicated a strong influence of biomass composition
on the behavior of biocomposites under γ-irradiation. The high
γ-irradiation dose influences the properties of PP biocomposites.
The contact angle values of irradiated samples decreased with respect
to unirradiated PP/biomass composites, indicating an improved surface
hydrophilicity. The chemiluminescence study revealed the capability
of biomass to delay long-term oxidative degradation. The durability
of these products is enhanced because of the protective role of lignin,
which acts as an antioxidant due to its phenol–propanoic structure.
The lignin activity depends on its content in biomass incorporated
in polypropylene. Therefore, according to the increase in antioxidant
quality, the studied biomasses were placed in the sequence Eucalyptus globulus ∼ pine cones > Brassica
rapa, which corresponds with decreased lignin content in
biomass samples.