Studies on heterocyclic ketenethioacetal derivatives. VII. Reactions of 3-ethyl-5-bis(methylthio)methylene-2-thioxothiazol-4(5H)-one.

Tominaga, Yoshinori; Sone, M.; Mizuyama, Kazumichi; Matsuda, Yoshiro; Kobayashi, Gorô

doi:10.1248/cpb.24.1671

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“…117 However, 4-thiazolidinones on treatment with 30% H202 in a mixture of cold acetic acid and acetic anhydride give the 4-thiazolidinone S-monooxide deriva-tives210 (202). 2-(Arylimino)-3-substituted-4-thiazolidinones and 2,3-disubstituted-4-thiazolidinones are oxidized to the corresponding 1,1-dioxides (203,204) on treatment with KMn04 in glacial acetic acid at 0 °C.39,52,53,119…”

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confidence: 99%

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Chemistry and biological activity of thiazolidinones

Singh¹,

Parmar²,

Raman³

et al. 1981

Chem. Rev.

398

183

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confidence: 99%

“…et al203 have reported the reaction of3- ethylrhodanine with carbon disulfide in the presence of sodium hydroxide in dimethyl sulfoxide, giving 3ethyl-5-[bis(methylthio)methylene]-2-thioxo-4-thiazolidinone (184). This on treatment with nucleophilic as amines or active methylenes yields the corresponding replacement products of one…”

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confidence: 99%