“…Despite the fact that careful assignment of the characteristic UV, 1 H-and 13 C-magnetic resonance data can distinguish the two isomers, there are occasions when investigators have concluded wrongly about the structure of their isolates 29 . For instance, 7-O-β-D-glucopyranosyl-6-C-β-D-glucopyranosylapigenin (saponarin) has been reported to occur in mature barley (Hordeum vulgare) leaves, along with lutonarin and its 3'-hydroxylated analogue [29][30][31] . A number of publications have described the structure of this glycoflavone, isolated from young green barley leaves, as 2"-O-β-Dglucopyranosyl-6-C-β-D-glucopyranosylapigenin (5) 32-…”