2001
DOI: 10.1179/026708301101509728
|View full text |Cite
|
Sign up to set email alerts
|

Study of deoxidation of 2024-T3 with various acids

Abstract: Sheet aluminium 2024-T3 alloy was treated in a range of acid solutions. These acid solutions included HNO 3 , H 2 SO 4 , and H 3 PO 4 alone, with HF, and with a combination of the oxidant sodium persulphate (Na 2 S 2 O 8 ) and HF. Changes in the surface chemistry and morphology of the matrix and intermetallics were characterised by scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDXS), Rutherford backscattering spectroscopy (RBS), and X-ray photoelectron spectroscopy (XPS). Etch rates… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
1
1
1
1

Citation Types

0
13
0

Year Published

2004
2004
2024
2024

Publication Types

Select...
5
2

Relationship

2
5

Authors

Journals

citations
Cited by 26 publications
(13 citation statements)
references
References 15 publications
0
13
0
Order By: Relevance
“…This shows that the acidic cleaning process has been considered to remove surface intermetallics and the corrosion products formed on the aluminium surface after alkaline etching. This can result in the decrease of galvanic couples and corrosion current density and the shift of corrosion potential toward more negative values compared to S2 [19,20]. In addition, the difference between E pitt and E corr for the method 3 is higher than other methods, indicating the increase of pitting generation resistance as a result of the decrease in the cathodic sites after acidic cleaning.…”
Section: Samplementioning
confidence: 80%
“…This shows that the acidic cleaning process has been considered to remove surface intermetallics and the corrosion products formed on the aluminium surface after alkaline etching. This can result in the decrease of galvanic couples and corrosion current density and the shift of corrosion potential toward more negative values compared to S2 [19,20]. In addition, the difference between E pitt and E corr for the method 3 is higher than other methods, indicating the increase of pitting generation resistance as a result of the decrease in the cathodic sites after acidic cleaning.…”
Section: Samplementioning
confidence: 80%
“…No associated features could be detected in x-ray maps of the surface, although 24 observed Cu enrichment at the metal/oxide interface in anodized coatings and Hughes et al 25 observed Cu enrichment in the thin surface oxide remaining after desmutting of AA2024-T3 in HNO 3 /HF desmutters. Thus, thinning of the surface oxide on the ridge of the rolling marks may expose cathodic material, which promotes H 2 O 2 reduction and ceria deposition.…”
Section: Ceria Deposition Onto Rolling Marksmentioning
confidence: 95%
“…In interpreting the deoxidation results, it is useful to consider deoxidation as a three-stage process: 15,37 (1) Activation through selective dissolution of the original oxide remaining after alkaline cleaning. Deoxidation for 1 min Figure 3 shows a series of six AFM images (at two magnifications) of the surface after 1, 5 and 10 min of deoxidation.…”
Section: Resultsmentioning
confidence: 99%