Objective: Photogalvanic (PG) cells are based on solar storage concepts. Hence, the objective of the research work is to enhance the solar energy conversion into electricity and store through PG cells for better electrical output. Methods: The PG cell setup consists of two electrode, digital pH meter, resistance key, carbon pot, and micro -ammeter. The specially designed H shaped PG cell was studied for better electrical having EDTA+TB+NaLS system. The significant impact of solar energy was studied by varying the various parameters in PG cell. The 25 ml solution of surfactant (07 ml), reductant (04 ml) and dye (13 ml) and distilled water with alkali were used for the PG cell. The designed PG cell is experimentally proved to be an efficient system with reference to enhanced electrical outcomes of renewable energy. Findings: For EDTA+TB+NaLS PG cell, the observed maximum photopotential and maximum photocurrent were 1065.00 mVand150.00 mA, respectively. The PG cell performance and efficacy were found 24.00 minutes and 0.2630%, respectively. Novelty: A proposed photochemical mechanism for solar radiation energy transformation in PG cells enhances significant electrical output by using of EDTA+TB+NaLS PG cell system.